Artículo

A mesoionic carbene complex of manganese in five oxidation states

Wittwer, Benjamin; Dickmann, Nicole; Berg, Stephan; Leitner, Daniel; Tesi, Lorenzo; Hunger, David; Gratzl, Raphael; van Slageren, Joris; Neuman, Nicolás IgnacioIcon ; Munz, Dominik; Hohloch, Stephan
Fecha de publicación: 04/2022
Editorial: Royal Society of Chemistry
Revista: Chemical Communications
ISSN: 1359-7345
Idioma: Inglés
Tipo de recurso: Artículo publicado
Clasificación temática:

Resumen

Reaction between a carbazole-based mesoionic carbene ligand and manganese(ii) iodide results in the formation of a rare air-stable manganese(iv) complex after aerobic workup. Cyclic voltammetry reveals the complex to be stable in five oxidation states. The electronic structure of all five oxidation states is elucidated chemically, spectroscopically (NMR, high-frequency EPR, UV-Vis, MCD), magnetically, and computationally (DFT, CASSCF).
Palabras clave: MESOIONIC , CARBENE , MANGANESE , CARBAZOLE
 
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info:eu-repo/semantics/openAccess Excepto donde se diga explícitamente, este item se publica bajo la siguiente descripción: Creative Commons Attribution-NonCommercial 2.5 Unported (CC BY-NC 2.5)
Identificadores
URI: http://hdl.handle.net/11336/216206
DOI: http://dx.doi.org/10.1039/D2CC00097K
URL: https://pubs.rsc.org/en/content/articlelanding/2022/CC/D2CC00097K
Colecciones
Articulos(INTEC)
Articulos de INST.DE DES.TECNOL.PARA LA IND.QUIMICA (I)
Citación
Wittwer, Benjamin; Dickmann, Nicole; Berg, Stephan; Leitner, Daniel; Tesi, Lorenzo; et al.; A mesoionic carbene complex of manganese in five oxidation states; Royal Society of Chemistry; Chemical Communications; 58; 41; 4-2022; 6096-6099
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