Artículo
Ar-Matrix Studies of the Photochemical Reaction between CS2 and ClF: Prereactive Complexes and Bond Isomerism of the Photoproducts
Custodio Castro, Michelle Tatiana
; Della Vedova, Carlos Omar
; Willner, Helge; Romano, Rosana Mariel
Fecha de publicación:
09/2022
Editorial:
Multidisciplinary Digital Publishing Institute
Revista:
Photochem
ISSN:
2673-7256
Idioma:
Inglés
Tipo de recurso:
Artículo publicado
Clasificación temática:
Resumen
In this work, prereactive complexes, reaction products, and conformational preferences derived from the photochemical reaction between CS2 and ClF were analyzed following the codeposition of the reactants trapped in argon matrices at cryogenic temperatures. After codeposition of CS2 and ClF diluted in Ar, the formation of van der Waals complexes is observed. When the mixture is subsequently irradiated by means of broad-band UV-visible light (225 800 nm), fluorothiocarbonylsulfenyl chloride (FC(S)SCl) and chlorothiocarbonylsulfenyl fluoride (ClC(S)SF) are produced. These species exist as two stable planar anti- and syn-conformers (anti- and syn- of the C=S double bond with respect to the S?Cl or S?F single bond, respectively). For both novel molecules, anti-FC(S)SCl and anti-ClC(S)SF are the lowest-energy computed rotamers. As expected due to the photochemical activity of these species, additional reaction products due to alternative or subsequent photochannels are formed during this process.
Palabras clave:
MATRIX-ISOLATION
,
PHOTOCHEMISTRY
,
CARBON-DISULFIDE
,
CHLOROMONOFLUORIDE
Archivos asociados
Licencia
Identificadores
Colecciones
Articulos(CCT - LA PLATA)
Articulos de CTRO.CIENTIFICO TECNOL.CONICET - LA PLATA
Articulos de CTRO.CIENTIFICO TECNOL.CONICET - LA PLATA
Articulos(CEQUINOR)
Articulos de CENTRO DE QUIMICA INORGANICA "DR. PEDRO J. AYMONINO"
Articulos de CENTRO DE QUIMICA INORGANICA "DR. PEDRO J. AYMONINO"
Citación
Custodio Castro, Michelle Tatiana; Della Vedova, Carlos Omar; Willner, Helge; Romano, Rosana Mariel; Ar-Matrix Studies of the Photochemical Reaction between CS2 and ClF: Prereactive Complexes and Bond Isomerism of the Photoproducts; Multidisciplinary Digital Publishing Institute; Photochem; 2; 3; 9-2022; 765-778
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