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dc.contributor.author
Tonutti, Lucas Gabriel
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dc.contributor.author
Maquirriain, Maira Alejandra
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dc.contributor.author
Querini, Carlos Alberto
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dc.contributor.author
Dalla Costa, Bruno Oscar
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dc.date.available
2023-09-15T11:36:28Z
dc.date.issued
2022-08
dc.identifier.citation
Tonutti, Lucas Gabriel; Maquirriain, Maira Alejandra; Querini, Carlos Alberto; Dalla Costa, Bruno Oscar; Synthesis of sulfonic SBA-15 by co-condensation and soxhlet extraction: optimization by shortening the preparation time; Springer; Journal of Porous Materials; 30; 1; 8-2022; 33-42
dc.identifier.issn
1380-2224
dc.identifier.uri
http://hdl.handle.net/11336/211594
dc.description.abstract
Propyl sulfonic SBA-15 catalysts are of great interest in several fields of chemistry and have exhibited high activity towards numerous reactions. Nonetheless, the incorporation of these functional groups on SBA-15 silica poses several challenges. Grafting techniques may conduct to a non-uniform dispersion of the functional groups on the surface. Co-condensation of the functional precursor during the synthesis of the silica overcomes this drawback, but requires longer syntheses and it has the disadvantage that removal of surfactant cannot be done by calcination because of the thermal stability of the functional groups present on the surface. Thus, the detemplation is limited in this case to extraction by standard procedures which generally involve large amounts of solvent per gram of catalyst, long contact time and limited yield of the template removal. The aims of this work were, on the one hand, to study the reduction of the ripening time for catalysts prepared by co-condensation with sulfonic groups and, on the other hand, to develop a standard procedure which allows achieving a high yield of detemplation and optimizes the amount of solvent needed and the time required, as well as employ a commercially available solvent. Different characterization techniques allowed to conclude that the obtained materials exhibited high surface area and a good degree of mesoscopic order, comparable with materials obtained by traditional procedures. Also, a high degree of template removal was achieved and the sulfonic groups were preserved in functionalized materials. These results are relevant for a further scale-up of the catalysts production.
dc.format
application/pdf
dc.language.iso
eng
dc.publisher
Springer
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dc.rights
info:eu-repo/semantics/restrictedAccess
dc.rights.uri
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.subject
COMMERCIAL SOLVENT
dc.subject
SHORT TIME SYNTHESIS
dc.subject
SOXHLET EXTRACTION
dc.subject
SULFONIC SBA-15
dc.subject.classification
Otras Ingeniería Química
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dc.subject.classification
Ingeniería Química
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dc.subject.classification
INGENIERÍAS Y TECNOLOGÍAS
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dc.title
Synthesis of sulfonic SBA-15 by co-condensation and soxhlet extraction: optimization by shortening the preparation time
dc.type
info:eu-repo/semantics/article
dc.type
info:ar-repo/semantics/artículo
dc.type
info:eu-repo/semantics/publishedVersion
dc.date.updated
2023-07-07T20:44:53Z
dc.journal.volume
30
dc.journal.number
1
dc.journal.pagination
33-42
dc.journal.pais
Alemania
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dc.description.fil
Fil: Tonutti, Lucas Gabriel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina
dc.description.fil
Fil: Maquirriain, Maira Alejandra. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina
dc.description.fil
Fil: Querini, Carlos Alberto. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina
dc.description.fil
Fil: Dalla Costa, Bruno Oscar. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina
dc.journal.title
Journal of Porous Materials
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dc.relation.alternativeid
info:eu-repo/semantics/altIdentifier/url/https://link.springer.com/article/10.1007/s10934-022-01321-2
dc.relation.alternativeid
info:eu-repo/semantics/altIdentifier/doi/http://dx.doi.org/10.1007/s10934-022-01321-2
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