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dc.contributor.author
Castellanos Buitrago, Nicolás Stiven
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dc.contributor.author
Villa, Aída Luz
dc.date.available
2023-09-15T11:28:50Z
dc.date.issued
2022-12
dc.identifier.citation
Castellanos Buitrago, Nicolás Stiven; Villa, Aída Luz; Heat capacity of some terpenes in the temperature range between (293.15 and 353.15) K and at 85.1 kPa; Academic Press Ltd - Elsevier Science Ltd; Journal of Chemical Thermodynamics; 179; 12-2022; 1-25
dc.identifier.issn
0021-9614
dc.identifier.uri
http://hdl.handle.net/11336/211588
dc.description.abstract
The heat capacity of several terpenes ((−)-carveol, (1R)-(−)-nopyl acetate, γ-terpinene, carvacrol, 3 carene, (1R)-(−)-myrtenol, (S)-(−)-perillyl alcohol, α-pinene oxide and (+)-limonene oxide) were estimated at Medellín (Colombia) atmospheric pressure and in the temperature range from 293.15 K to 353.15 K with a heating rate of 0.5 K/min. All measurements were performed by means of a Setaram E/μDSC 7 Evo-1A microcalorimeter. Heat capacities dependence with temperature were fitted to a third order polynomial equation. Furthermore, heat capacities were estimated using group contribution with Dvorkin et al model, the Dadgostar–Shaw universal correlation and a modified correlation of Dadgostar-Shaw and compared with experimental data. The reliability of the results was evaluated using water as a known substance; the experimental uncertainty measured using naphthalene was lower than 1.5 %.
dc.format
application/pdf
dc.language.iso
eng
dc.publisher
Academic Press Ltd - Elsevier Science Ltd
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dc.rights
info:eu-repo/semantics/openAccess
dc.rights.uri
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.subject
HEAT CAPACITY
dc.subject
MICRO DSC
dc.subject
TEMPERATURE EFFECT
dc.subject
TERPENES
dc.subject.classification
Ingeniería Química
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dc.subject.classification
Ingeniería Química
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dc.subject.classification
INGENIERÍAS Y TECNOLOGÍAS
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dc.title
Heat capacity of some terpenes in the temperature range between (293.15 and 353.15) K and at 85.1 kPa
dc.type
info:eu-repo/semantics/article
dc.type
info:ar-repo/semantics/artículo
dc.type
info:eu-repo/semantics/publishedVersion
dc.date.updated
2023-07-07T20:57:08Z
dc.journal.volume
179
dc.journal.pagination
1-25
dc.journal.pais
Estados Unidos
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dc.description.fil
Fil: Castellanos Buitrago, Nicolás Stiven. Universidad de Antioquia; Colombia. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina
dc.description.fil
Fil: Villa, Aída Luz. Universidad de Antioquia; Colombia
dc.journal.title
Journal of Chemical Thermodynamics
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dc.relation.alternativeid
info:eu-repo/semantics/altIdentifier/url/https://linkinghub.elsevier.com/retrieve/pii/S0021961422002622
dc.relation.alternativeid
info:eu-repo/semantics/altIdentifier/doi/http://dx.doi.org/10.1016/j.jct.2022.106983
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