Artículo
Synthesis of MOF-5 using terephthalic acid as a ligand obtained from polyethylene terephthalate (PET) waste and its test in CO2 adsorption
Villarroel Rocha, Dimar
; Bernini, Maria Celeste
; Arroyo Gómez, José Joaquín; Villarroel Rocha, Jhonny
; Sapag, Manuel Karim
Fecha de publicación:
01/2022
Editorial:
Brazilian Society of Chemical Engineering
Revista:
Brazilian Journal of Chemical Engineering
ISSN:
0104-6632
e-ISSN:
1678-4383
Idioma:
Inglés
Tipo de recurso:
Artículo publicado
Clasificación temática:
Resumen
In this work, we present the preparation of MOF-5 using terephthalic acid as a ligand obtained from polyethylene terephthalate waste. The results showed that the obtained terephthalic acid gave similar features to the commercial one. The synthesized MOF was fully characterized and tested for CO2 adsorption at 35 °C and at atmospheric pressure, under static and dynamic conditions, presenting adsorption capacities of 2.5 and 2 mmol g−1, respectively, which are higher than the reported values. At 1000 kPa, in static conditions, the adsorption capacity was 7.8 mmol g−1. The obtained results demonstrated that this MOF presented improved structural stability and CO2 adsorption capacity compared with the results reported elsewhere.
Palabras clave:
METAL ORGANIC FRAMEWORKS
,
GAS ADSORPTION
,
PET WASTE
,
ADDING VALUE
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Identificadores
Colecciones
Articulos(INTEQUI)
Articulos de INST. DE INVEST. EN TECNOLOGIA QUIMICA
Articulos de INST. DE INVEST. EN TECNOLOGIA QUIMICA
Citación
Villarroel Rocha, Dimar; Bernini, Maria Celeste; Arroyo Gómez, José Joaquín; Villarroel Rocha, Jhonny; Sapag, Manuel Karim; Synthesis of MOF-5 using terephthalic acid as a ligand obtained from polyethylene terephthalate (PET) waste and its test in CO2 adsorption; Brazilian Society of Chemical Engineering; Brazilian Journal of Chemical Engineering; 39; 4; 1-2022; 949-959
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