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dc.contributor.author
Marcinkowski, Dawid
dc.contributor.author
Adamski, Ariel
dc.contributor.author
Kubicki, Maciej
dc.contributor.author
Consiglio, Giuseppe
dc.contributor.author
Patroniak, Violetta
dc.contributor.author
Ślusarski, Tomasz
dc.contributor.author
Açıkgöz, Muhammed
dc.contributor.author
Szeliga, Daria
dc.contributor.author
Vadra, Nahir
dc.contributor.author
Karbowiak, Mirosław
dc.contributor.author
Stefaniuk, Ireneusz
dc.contributor.author
Rudowicz, Czesław
dc.contributor.author
Gorczy?ski, Adam
dc.contributor.author
Korabik, Maria
dc.date.available
2023-09-01T16:45:00Z
dc.date.issued
2022-09
dc.identifier.citation
Marcinkowski, Dawid; Adamski, Ariel; Kubicki, Maciej; Consiglio, Giuseppe; Patroniak, Violetta; et al.; Understanding the effect of structural changes on slow magnetic relaxation in mononuclear octahedral copper(ii) complexes; Royal Society of Chemistry; Dalton Transactions; 51; 32; 9-2022; 12041-12055
dc.identifier.issn
1477-9226
dc.identifier.uri
http://hdl.handle.net/11336/210202
dc.description.abstract
Current advances in molecular magnetism are aimed at the construction of molecular nanomagnets and spin qubits for their utilization as high-density data storage materials and quantum computers. Mononuclear coordination compounds with low spin values of S = ½ are excellent candidates for this endeavour, but knowledge of their construction via rational design is limited. This particularly applies to the single copper(ii) spin center, having been only recently demonstrated to exhibit slow relaxation of magnetisation in the appropriate octahedral environment. We have thus prepared a unique organic scaffold that would allow one to gain in-depth insight into how purposeful structural differences affect the slow magnetic relaxation in monometallic, transition metal complexes. As a proof-of-principle, we demonstrate how one can construct two, structurally very similar complexes with isolated Cu(ii) ions in an octahedral ligand environment, the magnetic properties of which differ significantly. The differences in structural symmetry effects and in magnetic relaxation are corroborated with a series of experimental techniques and theoretical approaches, showing how symmetry distortions and crystal packing affect the relaxation behaviour in these isolated Cu(ii) systems. Our unique organic platform can be efficiently utilized for the construction of various transition-metal ion systems in the future, effectively providing a model system for investigation of magnetic relaxation via targeted structural distortions.
dc.format
application/pdf
dc.language.iso
eng
dc.publisher
Royal Society of Chemistry
dc.rights
info:eu-repo/semantics/openAccess
dc.rights.uri
https://creativecommons.org/licenses/by/2.5/ar/
dc.subject
slow magnetic relaxation
dc.subject.classification
Química Inorgánica y Nuclear
dc.subject.classification
Ciencias Químicas
dc.subject.classification
CIENCIAS NATURALES Y EXACTAS
dc.title
Understanding the effect of structural changes on slow magnetic relaxation in mononuclear octahedral copper(ii) complexes
dc.type
info:eu-repo/semantics/article
dc.type
info:ar-repo/semantics/artículo
dc.type
info:eu-repo/semantics/publishedVersion
dc.date.updated
2023-07-10T11:13:10Z
dc.journal.volume
51
dc.journal.number
32
dc.journal.pagination
12041-12055
dc.journal.pais
Reino Unido
dc.journal.ciudad
Cambridge
dc.description.fil
Fil: Marcinkowski, Dawid. Adam Mickiewicz University; Polonia
dc.description.fil
Fil: Adamski, Ariel. Adam Mickiewicz University; Polonia
dc.description.fil
Fil: Kubicki, Maciej. Adam Mickiewicz University; Polonia
dc.description.fil
Fil: Consiglio, Giuseppe. Università Degli Studi Di Catania; Italia
dc.description.fil
Fil: Patroniak, Violetta. Adam Mickiewicz University; Polonia
dc.description.fil
Fil: Ślusarski, Tomasz. Adam Mickiewicz University; Polonia
dc.description.fil
Fil: Açıkgöz, Muhammed. No especifíca;
dc.description.fil
Fil: Szeliga, Daria. No especifíca;
dc.description.fil
Fil: Vadra, Nahir. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Instituto de Química, Física de los Materiales, Medioambiente y Energía. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Instituto de Química, Física de los Materiales, Medioambiente y Energía; Argentina
dc.description.fil
Fil: Karbowiak, Mirosław. No especifíca;
dc.description.fil
Fil: Stefaniuk, Ireneusz. No especifíca;
dc.description.fil
Fil: Rudowicz, Czesław. Adam Mickiewicz University; Polonia
dc.description.fil
Fil: Gorczy?ski, Adam. Adam Mickiewicz University; Polonia
dc.description.fil
Fil: Korabik, Maria. No especifíca;
dc.journal.title
Dalton Transactions
dc.relation.alternativeid
info:eu-repo/semantics/altIdentifier/doi/http://dx.doi.org/10.1039/d2dt01564a
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