Artículo
Solid-State Characterization of Acetylpyridine Copper Complexes for the Activation Of H2O2 in Advanced Oxidation Processes
Crespi, Ayelen Florencia; Zomero, Paula N.; Sanchez, Veronica Muriel
; Pérez, Ana Laura
; Brondino, Carlos Dante
; Vega, Daniel Roberto; Rodríguez Castellón, Enrique; Lazaro Martinez, Juan Manuel
Fecha de publicación:
06/2022
Editorial:
Wiley VCH Verlag
Revista:
Chemphyschem
ISSN:
1439-4235
e-ISSN:
2192-6506
Idioma:
Inglés
Tipo de recurso:
Artículo publicado
Clasificación temática:
Resumen
This work describes the synthesis of 4-(4-AcPy) and 3-acetylpyridine (3-AcPy) copper soluble complexes for the activation of hydrogen peroxide and the concomitant generation of reactive oxygen species (ROS). Given the paramagnetic effects of copper ions in the Nuclear Magnetic Resonance (NMR) lines, we aimed at demonstrating that the combination of high-resolution 2D solid-state NMR experiments, Electron Paramagnetic Resonance (EPR), single-crystal X-ray crystallography and Density Functional Theory (DFT) calculations allows a detailed study of the chemical structure of the ligands and the surrounding metal ions. The copper complexes synthesized with CuCl2 were useful for the activation of H2O2 during which the only ROS was the hydroxyl one, as demonstrated by EPR experiments. A removal of methyl orange (MO) azo-dye higher than 85 % was achieved in 200 minutes, combining 1.7 mM of copper complexes with 60 mM of H2O2 and 40 μM of MO.
Palabras clave:
COPPER
,
DFT
,
EPR
,
SOLID-STATE NMR
,
X-RAY CRYSTALLOGRAPHY
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Colecciones
Articulos(CCT - SANTA FE)
Articulos de CTRO.CIENTIFICO TECNOL.CONICET - SANTA FE
Articulos de CTRO.CIENTIFICO TECNOL.CONICET - SANTA FE
Articulos(IFIS - LITORAL)
Articulos de INST.DE FISICA DEL LITORAL
Articulos de INST.DE FISICA DEL LITORAL
Articulos(INQUIMAE)
Articulos de INST.D/QUIM FIS D/L MATERIALES MEDIOAMB Y ENERGIA
Articulos de INST.D/QUIM FIS D/L MATERIALES MEDIOAMB Y ENERGIA
Articulos(IQUIMEFA)
Articulos de INST.QUIMICA Y METABOLISMO DEL FARMACO (I)
Articulos de INST.QUIMICA Y METABOLISMO DEL FARMACO (I)
Citación
Crespi, Ayelen Florencia; Zomero, Paula N.; Sanchez, Veronica Muriel; Pérez, Ana Laura; Brondino, Carlos Dante; et al.; Solid-State Characterization of Acetylpyridine Copper Complexes for the Activation Of H2O2 in Advanced Oxidation Processes; Wiley VCH Verlag; Chemphyschem; 87; 7; 6-2022; 1-12
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