Artículo
Dielectric properties of 3-3 flexible composites by infiltration of elastomers into porous ceramic structures using cellulose scaffold
Levy, Ivana Karina
; Owussu, Francis; Geiger, Thomas; Clemmens, Frank; Nüesch, Frank; Opris, Dorina M.; Negri, Ricardo Martin
Fecha de publicación:
10/2022
Editorial:
Pergamon-Elsevier Science Ltd
Revista:
European Polymer Journal
ISSN:
0014-3057
Idioma:
Inglés
Tipo de recurso:
Artículo publicado
Clasificación temática:
Resumen
Elastomer composites are prepared by infiltrating polydimethylsiloxane (PDMS) into a porous ceramic structure of nanoparticles. This method differs from the conventional approach, where particles are dispersed into the polymer matrix, since here, the polymer is incorporated into a pre-sintered structure of nanoparticles by infiltration under vacuum. Several oxides (CoFe2O4, ZnO, BaTiO3, BiFeO3, and BiFeO3 doped with yttrium), commonly used for dielectric and piezoelectric devices, were infiltrated by PDMS. The porous 3D structure of nanoparticles is obtained by using cellulose as a scaffold and binder, which is eliminated during the process. Thus, the so-called (3,3) composites are obtained, where the particles are in direct contact (although immersed in the polymer), at relatively low loading. The dielectric behaviour of the infiltrated and conventional composites is determined by impedance spectroscopy, dielectric polarization analysis, determinations of electric breakdown-field (EBD), and static dielectric constant (εs). The percentage increase of εs from conventional to infiltrated composites is remarkable, reaching for BiFeO3-Y, an increase of εs and ε′(ω) larger than 600 %, while EBD decreases by a factor of 3.
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Articulos(INQUIMAE)
Articulos de INST.D/QUIM FIS D/L MATERIALES MEDIOAMB Y ENERGIA
Articulos de INST.D/QUIM FIS D/L MATERIALES MEDIOAMB Y ENERGIA
Citación
Levy, Ivana Karina; Owussu, Francis; Geiger, Thomas; Clemmens, Frank; Nüesch, Frank; et al.; Dielectric properties of 3-3 flexible composites by infiltration of elastomers into porous ceramic structures using cellulose scaffold; Pergamon-Elsevier Science Ltd; European Polymer Journal; 180; 10-2022; 1-10
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