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dc.contributor.author
Yerien, Damián Emilio  
dc.contributor.author
Postigo, Jose Alberto  
dc.contributor.author
Baroncini, Massimo  
dc.contributor.author
Barata Vallejo, Sebastian  
dc.date.available
2023-08-16T18:38:07Z  
dc.date.issued
2021-10  
dc.identifier.citation
Yerien, Damián Emilio; Postigo, Jose Alberto; Baroncini, Massimo; Barata Vallejo, Sebastian; Bioinspired photocatalysed C-H fluoroalkylation of arenes in water promoted by native vitamin B12and Rose Bengal; Royal Society of Chemistry; Green Chemistry (print); 23; 20; 10-2021; 8147-8153  
dc.identifier.issn
1463-9262  
dc.identifier.uri
http://hdl.handle.net/11336/208504  
dc.description.abstract
The first perfluoroalkylation reaction of activated arenes (amino-substituted arenes and alkoxyarenes) has been achieved in water by employing the dyad Rose Bengal and hydrosoluble unmodified vitamin B12 (cyanocobalamin) as the photocatalyst and co-catalyst, respectively. The reaction was performed under green LED irradiation and employed perfluoroalkyl bromides as the perfluoroalkyl radical sources. In particular, the presence of vitamin B12 co-catalyst was found to be fundamental to elicit the formation of perfluoroalkyl radicals.  
dc.format
application/pdf  
dc.language.iso
eng  
dc.publisher
Royal Society of Chemistry  
dc.rights
info:eu-repo/semantics/restrictedAccess  
dc.rights.uri
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/  
dc.subject
FLUOROALKYLATION  
dc.subject.classification
Química Orgánica  
dc.subject.classification
Ciencias Químicas  
dc.subject.classification
CIENCIAS NATURALES Y EXACTAS  
dc.title
Bioinspired photocatalysed C-H fluoroalkylation of arenes in water promoted by native vitamin B12and Rose Bengal  
dc.type
info:eu-repo/semantics/article  
dc.type
info:ar-repo/semantics/artículo  
dc.type
info:eu-repo/semantics/publishedVersion  
dc.date.updated
2023-08-11T10:44:14Z  
dc.journal.volume
23  
dc.journal.number
20  
dc.journal.pagination
8147-8153  
dc.journal.pais
Reino Unido  
dc.journal.ciudad
Cambridge  
dc.description.fil
Fil: Yerien, Damián Emilio. Universidad de Buenos Aires. Facultad de Farmacia y Bioquímica; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina  
dc.description.fil
Fil: Postigo, Jose Alberto. Universidad de Buenos Aires. Facultad de Farmacia y Bioquímica; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina  
dc.description.fil
Fil: Baroncini, Massimo. Università di Bologna; Italia  
dc.description.fil
Fil: Barata Vallejo, Sebastian. Universidad de Buenos Aires. Facultad de Farmacia y Bioquímica; Argentina. Consiglio Nazionale delle Ricerche; Italia. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina  
dc.journal.title
Green Chemistry (print)  
dc.relation.alternativeid
info:eu-repo/semantics/altIdentifier/url/http://pubs.rsc.org/en/Content/ArticleLanding/2021/GC/D1GC02654B  
dc.relation.alternativeid
info:eu-repo/semantics/altIdentifier/doi/http://dx.doi.org/10.1039/D1GC02654B  

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