Synthesis, X-ray Structures, and spectroscopic characterization of cis and trans-bis(O-propyldithiocarbonato)bis(pyridine)nickel(II), cis and trans-[Ni(CH3CH2CH2OC(S)S)2(C5H5N)2]

Single crystals of cis and trans-bis(O-propyldithiocarbonato)bis(pyridine)nickel(II), cis and trans-[Ni(CH3CH2CH2OC(S)S)2(C5H5N)2], have been prepared and studied using single crystal X-ray diffraction method and IR spectroscopy. The crystal structure of tetracoordinated Ni(II) xanthate complex, bis(O-propyldithiocarbonato)nickel(II), [Ni(CH3CH2CH2OC(S)S)2], was also determined and compared with the previously reported structure. The existence of a cis form for a hexacoordinated species of the [NiS4N2] type is infrequent for this family of complexes.

Palabras clave: Ni(II) complex , O-propyldithiocarbonato complex , Crystal Structure

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Excepto donde se diga explícitamente, este item se publica bajo la siguiente descripción: Atribución-NoComercial-SinDerivadas 2.5 Argentina (CC BY-NC-ND 2.5 AR)

Identificadores

URI: http://hdl.handle.net/11336/205234

URL: https://www.sciencedirect.com/science/article/abs/pii/S0009261422001543

DOI: http://dx.doi.org/10.1016/j.cplett.2022.139487

Colecciones

Articulos(CCT - LA PLATA)
Articulos de CTRO.CIENTIFICO TECNOL.CONICET - LA PLATA

Articulos(CEQUINOR)
Articulos de CENTRO DE QUIMICA INORGANICA "DR. PEDRO J. AYMONINO"

Articulos(IFLP)
Articulos de INST.DE FISICA LA PLATA

Citación

Juncal, Luciana Celeste; Ferrer, Evelina Gloria; Williams, Patricia Ana María; Boese, Roland; Pozzi, Carlos Gustavo; et al.; Synthesis, X-ray Structures, and spectroscopic characterization of cis and trans-bis(O-propyldithiocarbonato)bis(pyridine)nickel(II), cis and trans-[Ni(CH3CH2CH2OC(S)S)2(C5H5N)2]; Elsevier Science; Chemical Physics Letters; 794; 1394; 22-2-2022; 1-7

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