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dc.contributor.author
Rengifo Herrera, Julian Andres  
dc.contributor.author
Osorio Vargas, Paula Alejandra  
dc.contributor.author
Pulgarin, Cesar  
dc.date.available
2023-07-24T14:32:02Z  
dc.date.issued
2021-12-03  
dc.identifier.citation
Rengifo Herrera, Julian Andres; Osorio Vargas, Paula Alejandra; Pulgarin, Cesar; A critical review on N-modified TiO2 limits to treat chemical and biological contaminants in water. Evidence that enhanced visible light absorption does not lead to higher degradation rates under whole solar light; Elsevier Science; Journal of Hazardous Materials; 425; 3-12-2021; 1-23  
dc.identifier.issn
0304-3894  
dc.identifier.uri
http://hdl.handle.net/11336/205035  
dc.description.abstract
Intensive research has been focused on the synthesis of N-modified TiO2 materials having visible light absorption in order to get higher solar photocatalytic degradation rates of pollutants in water. However, an exhaustive revision of the topic underlines several controversial issues related to N-modified TiO2 materials; these issues concern (a) the methodology used for preparation, (b) the assessment of the structural characteristics, (c) the mechanistic action modes and (d) the raisons argued to explain the limited performances of the prepared materials for organic and biological targets photodegradation in water. Taking advantage of last year's progress in analytical chemistry and in material characterization methods, the authors show, for example, that some works in the literature controversially attribute the term nitrogen doping without enough analytical evidence. Additionally, some papers describe N-modified TiO2 photocatalysts as being able to generate holes with enough oxidative potential to form hydroxyl radicals under visible light. This last assertion often derives from a no pertinent use of illumination sources, light filters, or targets or a limited understanding of the thermodynamic aspects of the studied systems. None of N-containing materials prepared by herein presented methods leads, under solar light, to a significant enhancement in pollutants degradation and microorganism's inactivation kinetics.  
dc.format
application/pdf  
dc.language.iso
eng  
dc.publisher
Elsevier Science  
dc.rights
info:eu-repo/semantics/openAccess  
dc.rights.uri
https://creativecommons.org/licenses/by-nc-nd/2.5/ar/  
dc.subject
N-MODIFIED TIO2  
dc.subject
POLLUTANTS PHOTOCATALYTIC DEGRADATION  
dc.subject
VISIBLE LIGHT RESPONSE  
dc.subject
WATER TREATMENT  
dc.subject.classification
Físico-Química, Ciencia de los Polímeros, Electroquímica  
dc.subject.classification
Ciencias Químicas  
dc.subject.classification
CIENCIAS NATURALES Y EXACTAS  
dc.title
A critical review on N-modified TiO2 limits to treat chemical and biological contaminants in water. Evidence that enhanced visible light absorption does not lead to higher degradation rates under whole solar light  
dc.type
info:eu-repo/semantics/article  
dc.type
info:ar-repo/semantics/artículo  
dc.type
info:eu-repo/semantics/publishedVersion  
dc.date.updated
2023-07-07T18:41:51Z  
dc.journal.volume
425  
dc.journal.pagination
1-23  
dc.journal.pais
Países Bajos  
dc.journal.ciudad
Amsterdam  
dc.description.fil
Fil: Rengifo Herrera, Julian Andres. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigación y Desarrollo en Ciencias Aplicadas "Dr. Jorge J. Ronco". Universidad Nacional de la Plata. Facultad de Ciencias Exactas. Centro de Investigación y Desarrollo en Ciencias Aplicadas; Argentina  
dc.description.fil
Fil: Osorio Vargas, Paula Alejandra. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigación y Desarrollo en Ciencias Aplicadas "Dr. Jorge J. Ronco". Universidad Nacional de la Plata. Facultad de Ciencias Exactas. Centro de Investigación y Desarrollo en Ciencias Aplicadas; Argentina  
dc.description.fil
Fil: Pulgarin, Cesar. École Polytechnique Fédérale de Lausanne; Suiza  
dc.journal.title
Journal of Hazardous Materials  
dc.relation.alternativeid
info:eu-repo/semantics/altIdentifier/url/https://linkinghub.elsevier.com/retrieve/pii/S0304389421029484  
dc.relation.alternativeid
info:eu-repo/semantics/altIdentifier/doi/http://dx.doi.org/10.1016/j.jhazmat.2021.127979