Artículo

Structural characterization of the water-soluble porphyrin complexes [FeII(TPPS) (NO•)]4─ and [μ-O-([FeIII(TPPS)])2]8─

Mazzeo, Agostina MaríaIcon ; Gaviglio, Carina del ValleIcon ; Pellegrino, JuanIcon ; Doctorovich, FabioIcon
Fecha de publicación: 06/2022
Editorial: Elsevier
Revista: Heliyon
ISSN: 2405-8440
Idioma: Inglés
Tipo de recurso: Artículo publicado
Clasificación temática:

Resumen

Iron water-soluble porphyrins have been long used as biomimetic compounds for modelling the active sites found in heme-enzymes. In this regard, the anionic porphyrin [FeIII(TPPS)]3─ and its coordination complexes have been repeatedly chosen as suitable water-soluble platforms for bioinorganic chemistry studies. In this work we report for the first time the crystal structure of the water-soluble nitrosyl complex [FeII(TPPS) (NO•)]4─ along with that of oxodimeric ferric species [μ-O-([FeIII(TPPS)])2]8─.
Palabras clave: COORDINATION COMPLEX , CRYSTAL STRUCTURE , IRON NITROSYL , IRON PORPHYRIN , WATER-SOLUBLE
 
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info:eu-repo/semantics/openAccess Excepto donde se diga explícitamente, este item se publica bajo la siguiente descripción: Atribución-NoComercial-SinDerivadas 2.5 Argentina (CC BY-NC-ND 2.5 AR)
Identificadores
URI: http://hdl.handle.net/11336/201700
URL: https://www.cell.com/heliyon/fulltext/S2405-8440(22)00843-X
DOI: https://doi.org/10.1016/j.heliyon.2022.e09555
Colecciones
Articulos(SEDE CENTRAL)
Articulos de SEDE CENTRAL
Citación
Mazzeo, Agostina María; Gaviglio, Carina del Valle; Pellegrino, Juan; Doctorovich, Fabio; Structural characterization of the water-soluble porphyrin complexes [FeII(TPPS) (NO•)]4─ and [μ-O-([FeIII(TPPS)])2]8─; Elsevier; Heliyon; 8; 6; 6-2022; 1-9
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