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dc.contributor.author
Rengifo Herrera, Julian Andres
dc.contributor.author
Pierzchala, Katarzyna
dc.contributor.author
Sienkiewicz, Andrejz
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Forro, Lazlo
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Kiwi, Jhon
dc.contributor.author
Moser, Jacques E.
dc.contributor.author
Pulgarin, Cesar
dc.date.available
2017-07-05T15:54:46Z
dc.date.issued
2010-01-25
dc.identifier.citation
Rengifo Herrera, Julian Andres; Pierzchala, Katarzyna; Sienkiewicz, Andrejz; Forro, Lazlo; Kiwi, Jhon; et al.; Synthesis, characterization and photocatalytic activities of nanoparticulate N, S co-doped TiO2 having different surface-to-volume ratios; American Chemical Society; Journal Of Physical Chemistry C; 114; 6; 25-1-2010; 2717-2723
dc.identifier.issn
1932-7447
dc.identifier.uri
http://hdl.handle.net/11336/19592
dc.description.abstract
An efficient, visible light active, N, S-codoped TiO2-based photocatalyst was prepared by reacting thiourea with nanoparticulate anatase TiO2. Commercial anatase powders were manually ground with thiourea and annealed at 400 °C in two crucibles with different surface-to-volume ratios (S/V = 20 and 1.5) to prepare two N, S-codoped TiO2 materials. The differentiated aeration conditions during the catalyst annealing on the crucibles allowed for different amounts of O2 to reach the catalyst surface. The first material, with S/V = 20, herein referred to as D-TKP 102-A, was clear beige colored. The second material, with S/V = 1.5, herein referred to as D-TKP 102-B, was darker and revealed a markedly lower efficiency in Escherichia coli inactivation. The D-TKP 102-A powder presented visible light absorption due to the nitrogen (N) and sulfur (S) doping. X-ray photoelectron spectroscopy signals for this catalyst were observed for N 1s peaks at binding energies of 399.2 and 400.7 eV due to interstitial N-doping or Ti−O−N species. The S 2p were due to SO4−2 signals with BE >168 eV and signals at 162.8 and 167.2 eV due to anionic and cationic S-doping, respectively. By fast kinetic spectroscopy, the decay of the electron induced by pulsed light at λ = 450 nm (∼8 ns/laser pulse) was followed for the D-TKP 102-A catalyst. Undoped D-TKP 102 catalyst did not promote the electron in the visible range, and consequently no signal decay could be observed in the latter case. Low-temperature electron spin resonance measurements at 8 K provided evidence for electrons trapped in shallow traps, such as oxygen vacancies, Vo, induced by N, S doped on D-TKP 102-A. The ESR measurements implementing the reactive scavenging with singlet oxygen scavenger, TMP−OH, revealed the production of singlet oxygen (1O2).
dc.format
application/pdf
dc.language.iso
eng
dc.publisher
American Chemical Society
dc.rights
info:eu-repo/semantics/openAccess
dc.rights.uri
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.subject
Heterogeneous Photocatalysis
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Visible Light Response
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Nitrogen Doped Tio2
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Sulfur Doped Tio2
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E. Coli Inactivation
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Ingeniería Química
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Ingeniería Química
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INGENIERÍAS Y TECNOLOGÍAS
dc.title
Synthesis, characterization and photocatalytic activities of nanoparticulate N, S co-doped TiO2 having different surface-to-volume ratios
dc.type
info:eu-repo/semantics/article
dc.type
info:ar-repo/semantics/artículo
dc.type
info:eu-repo/semantics/publishedVersion
dc.date.updated
2015-10-30T18:20:28Z
dc.journal.volume
114
dc.journal.number
6
dc.journal.pagination
2717-2723
dc.journal.pais
Estados Unidos
dc.journal.ciudad
Washington
dc.description.fil
Fil: Rengifo Herrera, Julian Andres. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico La Plata. Centro de Investigación y Desarrollo en Ciencias Aplicadas; Argentina
dc.description.fil
Fil: Pierzchala, Katarzyna. Ecole Polytechnique Federale de Lausanne; Suiza
dc.description.fil
Fil: Sienkiewicz, Andrejz. Ecole Polytechnique Federale de Lausanne; Suiza
dc.description.fil
Fil: Forro, Lazlo. Ecole Polytechnique Federale de Lausanne; Suiza
dc.description.fil
Fil: Kiwi, Jhon. Ecole Polytechnique Federale de Lausanne; Suiza
dc.description.fil
Fil: Moser, Jacques E.. Ecole Polytechnique Federale de Lausanne; Suiza
dc.description.fil
Fil: Pulgarin, Cesar. Ecole Polytechnique Federale de Lausanne; Suiza
dc.journal.title
Journal Of Physical Chemistry C
dc.relation.alternativeid
info:eu-repo/semantics/altIdentifier/url/http://pubs.acs.org/doi/abs/10.1021/jp910486f
dc.relation.alternativeid
info:eu-repo/semantics/altIdentifier/doi/http://dx.doi.org/10.1021/jp910486f
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