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dc.contributor.author
Muñoz, Fernando Francisco  
dc.contributor.author
Leyva de Guglielmino, Ana Gabriela  
dc.contributor.author
Baker, Richard T.  
dc.contributor.author
Fuentes, Rodolfo Oscar  
dc.date.available
2023-03-23T19:33:05Z  
dc.date.issued
2012-10  
dc.identifier.citation
Muñoz, Fernando Francisco; Leyva de Guglielmino, Ana Gabriela; Baker, Richard T.; Fuentes, Rodolfo Oscar; Effect of preparation method on the properties of nanostructured gadolinia-doped ceria materials for IT-SOFCs; Pergamon-Elsevier Science Ltd; International Journal of Hydrogen Energy; 37; 19; 10-2012; 14854-14863  
dc.identifier.issn
0360-3199  
dc.identifier.uri
http://hdl.handle.net/11336/191657  
dc.description.abstract
In order to obtain different morphologies, nanostructured Gd 0.1Ce 0.9O 1.95 (GDC10) and Gd 0.2Ce 0.8O 1.90 (GDC20) were synthesized using three different chemical methods: reverse microemulsion (RM), cation complexation (CC) and template-filling (TF). The resulting materials were characterized by synchrotron radiation X-ray diffraction (SR-XRD), by X-ray absorption near-edge spectroscopy (XANES) and by scanning and high resolution transmission electron microscopy (SEM and HRTEM). All nanostructured mixed oxides were found to have a cubic crystal phase (Fm3m space group) with an average crystallite sizes ranging from 9.6 to 13.2 nm. Tubular nanostructured GDC10 obtained using a template-filling method exhibited the largest specific surface area (97 m 2 g -1) while the lowest values were obtained using the cation complexation method (23 m 2 g -1). XANES results indicated that the extent of reduction of these materials was small. Nevertheless, the Ce 3+ ion was detected. Preliminary catalytic studies showed that the tubular nanostructured (TF) GDC10 samples exhibited better catalytic activity for CH 4 oxidation than the CC and RM nanopowders of the same chemical composition.  
dc.format
application/pdf  
dc.language.iso
eng  
dc.publisher
Pergamon-Elsevier Science Ltd  
dc.rights
info:eu-repo/semantics/openAccess  
dc.rights.uri
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/  
dc.subject
HRTEM  
dc.subject
NANOSTRUCTURED CERIA-GADOLINIA SOLID SOLUTIONS  
dc.subject
SOLID OXIDE FUEL CELLS  
dc.subject
X-RAY ABSORPTION SPECTROSCOPY  
dc.subject
X-RAY POWDER DIFFRACTION  
dc.subject.classification
Físico-Química, Ciencia de los Polímeros, Electroquímica  
dc.subject.classification
Ciencias Químicas  
dc.subject.classification
CIENCIAS NATURALES Y EXACTAS  
dc.title
Effect of preparation method on the properties of nanostructured gadolinia-doped ceria materials for IT-SOFCs  
dc.type
info:eu-repo/semantics/article  
dc.type
info:ar-repo/semantics/artículo  
dc.type
info:eu-repo/semantics/publishedVersion  
dc.date.updated
2023-03-23T12:31:14Z  
dc.journal.volume
37  
dc.journal.number
19  
dc.journal.pagination
14854-14863  
dc.journal.pais
Países Bajos  
dc.journal.ciudad
Amsterdam  
dc.description.fil
Fil: Muñoz, Fernando Francisco. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Ministerio de Defensa. Instituto de Investigaciones Científicas y Técnicas para la Defensa; Argentina  
dc.description.fil
Fil: Leyva de Guglielmino, Ana Gabriela. Comisión Nacional de Energía Atómica; Argentina. Universidad Nacional de San Martín. Escuela de Ciencia y Tecnología; Argentina  
dc.description.fil
Fil: Baker, Richard T.. University of St. Andrews; Reino Unido  
dc.description.fil
Fil: Fuentes, Rodolfo Oscar. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Ministerio de Defensa. Instituto de Investigaciones Científicas y Técnicas para la Defensa; Argentina. Comisión Nacional de Energía Atómica; Argentina  
dc.journal.title
International Journal of Hydrogen Energy  
dc.relation.alternativeid
info:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/pii/S036031991102787X  
dc.relation.alternativeid
info:eu-repo/semantics/altIdentifier/doi/http://dx.doi.org/10.1016/j.ijhydene.2011.12.094