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dc.contributor.author
Saux, Clara  
dc.contributor.author
Pierella, Liliana Beatriz  
dc.date.available
2023-03-10T14:59:11Z  
dc.date.issued
2011-06  
dc.identifier.citation
Saux, Clara; Pierella, Liliana Beatriz; Studies on styrene selective oxidation to benzaldehyde catalyzed by Cr-ZSM-5: Reaction parameters effects and kinetics; Elsevier Science; Applied Catalysis A: General; 400; 1-2; 6-2011; 117-121  
dc.identifier.issn
0926-860X  
dc.identifier.uri
http://hdl.handle.net/11336/190197  
dc.description.abstract
The selective styrene oxidation to benzaldehyde was studied over Cr-ZSM-5 zeolite which was selected after probed a series of transition metal cations (chromium, cobalt, iron, zinc, manganese and cupper) using hydrogen peroxide as oxidant agent. The effects of various reaction parameters such as reaction time, catalyst mass, styrene/hydrogen peroxide molar ratio, solvent nature and reaction temperature effect were evaluated over it. Using the initial rate method, a first order with respect to styrene and oxidant concentrations was determined. An apparent activation energy of 14.54 kJ/mol was obtained.  
dc.format
application/pdf  
dc.language.iso
eng  
dc.publisher
Elsevier Science  
dc.rights
info:eu-repo/semantics/openAccess  
dc.rights.uri
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/  
dc.subject
BENZALDEHYDE  
dc.subject
CR-ZSM-5  
dc.subject
KINETIC PARAMETERS  
dc.subject
STYRENE OXIDATION  
dc.subject.classification
Ingeniería de Procesos Químicos  
dc.subject.classification
Ingeniería Química  
dc.subject.classification
INGENIERÍAS Y TECNOLOGÍAS  
dc.title
Studies on styrene selective oxidation to benzaldehyde catalyzed by Cr-ZSM-5: Reaction parameters effects and kinetics  
dc.type
info:eu-repo/semantics/article  
dc.type
info:ar-repo/semantics/artículo  
dc.type
info:eu-repo/semantics/publishedVersion  
dc.date.updated
2023-03-10T14:28:04Z  
dc.journal.volume
400  
dc.journal.number
1-2  
dc.journal.pagination
117-121  
dc.journal.pais
Países Bajos  
dc.journal.ciudad
Amsterdam  
dc.description.fil
Fil: Saux, Clara. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Centro de Investigación y Tecnología Química. Universidad Tecnológica Nacional. Facultad Regional Córdoba. Centro de Investigación y Tecnología Química; Argentina  
dc.description.fil
Fil: Pierella, Liliana Beatriz. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Centro de Investigación y Tecnología Química. Universidad Tecnológica Nacional. Facultad Regional Córdoba. Centro de Investigación y Tecnología Química; Argentina  
dc.journal.title
Applied Catalysis A: General  
dc.relation.alternativeid
info:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/abs/pii/S0926860X11002390  
dc.relation.alternativeid
info:eu-repo/semantics/altIdentifier/doi/http://dx.doi.org/10.1016/j.apcata.2011.04.021  

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