Artículo
XANES-PCA analysis of Ti-species in MCM-41 mesoporous silica synthesized by different method
Anunziata, Oscar Alfredo
; Beltramone, Andrea Raquel
; Martinez, Maria Laura
; Giovanetti, Lisandro Jose
; Requejo, Felix Gregorio
; Lede, Eduardo Javier
Fecha de publicación:
01/2011
Editorial:
Elsevier Science
Revista:
Applied Catalysis A: General
ISSN:
0926-860X
Idioma:
Inglés
Tipo de recurso:
Artículo publicado
Clasificación temática:
Resumen
MCM-41 mesoporous silica was prepared with Ti incorporated in the structure by two different ways: hydrothermal and atmospheric pressure by sol-gel method. To evaluate each synthesis, these materials were in situ investigated through X-ray absorption fine structure (XAFS) spectroscopy in different stages of the synthesis. X-ray absorption structure at the near edge region (XANES) gives the coordination of Ti and the relative concentration of Ti-species present in the mesoporous materials, obtained by different synthesis. The Principal Component Analysis (PCA) of XANES spectra indicate that mesoporous silica modified by Ti synthesized by hydrothermal method has species with majority of Ti tetrahedrally coordinated. This coordination is increased up to six when the sample is hydrated. In the case of the sol-gel synthesis, Ti-sites have higher mean coordination, independently from the degree of hydration.
Palabras clave:
HYDROTHERMAL SYNTHESIS
,
PCA/ITFA
,
SOL-GEL PROCEDURE
,
TI-K-XANES
,
TI-MCMC-41
Archivos asociados
Licencia
Identificadores
Colecciones
Articulos(CCT - CORDOBA)
Articulos de CTRO.CIENTIFICO TECNOL.CONICET - CORDOBA
Articulos de CTRO.CIENTIFICO TECNOL.CONICET - CORDOBA
Articulos(IFLP)
Articulos de INST.DE FISICA LA PLATA
Articulos de INST.DE FISICA LA PLATA
Citación
Anunziata, Oscar Alfredo; Beltramone, Andrea Raquel; Martinez, Maria Laura; Giovanetti, Lisandro Jose; Requejo, Felix Gregorio; et al.; XANES-PCA analysis of Ti-species in MCM-41 mesoporous silica synthesized by different method; Elsevier Science; Applied Catalysis A: General; 397; 1-2; 1-2011; 22-26
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