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dc.contributor.author
Riva, Jullieta Soledad  
dc.contributor.author
Girault, Hubert  
dc.contributor.author
Olaya, Astrid J.  
dc.date.available
2023-02-10T11:10:26Z  
dc.date.issued
2022-05  
dc.identifier.citation
Riva, Jullieta Soledad; Girault, Hubert; Olaya, Astrid J.; Water photo-oxidation on self-assembled organicCo3O4 metal junctions in biphasic systems; Pergamon-Elsevier Science Ltd; Electrochimica Acta; 414; 5-2022; 1-8  
dc.identifier.issn
0013-4686  
dc.identifier.uri
http://hdl.handle.net/11336/187554  
dc.description.abstract
A microwater|butyronitrile (W|BCN) interface was used to study the effect of the interfacial chemical polarization on the efficiency of the visible-light induced water oxidation reaction (WOR) by the electron acceptor/photosensitizer TTF/TTF•+self-assembled on the surface of Co3O4 microparticles, acting as redox electrocatalysts. The polarized W|BCN interface acts as a selective platform for the separation of the products of the photoreaction, TTF and protons, which has a strong positive effect on the efficiency of the WOR. The resulting cobalt oxide-organic microwire junction is as efficient as its Pt analog.  
dc.format
application/pdf  
dc.language.iso
eng  
dc.publisher
Pergamon-Elsevier Science Ltd  
dc.rights
info:eu-repo/semantics/restrictedAccess  
dc.rights.uri
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/  
dc.subject
LIQUID/LIQUID INTERFACES  
dc.subject
PHOTOCHEMISTRY  
dc.subject
TETRATHIAFULVALENE  
dc.subject
WATER OXIDATION  
dc.subject.classification
Físico-Química, Ciencia de los Polímeros, Electroquímica  
dc.subject.classification
Ciencias Químicas  
dc.subject.classification
CIENCIAS NATURALES Y EXACTAS  
dc.title
Water photo-oxidation on self-assembled organicCo3O4 metal junctions in biphasic systems  
dc.type
info:eu-repo/semantics/article  
dc.type
info:ar-repo/semantics/artículo  
dc.type
info:eu-repo/semantics/publishedVersion  
dc.date.updated
2023-02-09T15:47:31Z  
dc.journal.volume
414  
dc.journal.pagination
1-8  
dc.journal.pais
Estados Unidos  
dc.description.fil
Fil: Riva, Jullieta Soledad. Universidad Nacional de Córdoba. Facultad de Matemática, Astronomía y Física; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba; Argentina  
dc.description.fil
Fil: Girault, Hubert. Ecole Polytechnique Fédérale de Lausanne; Suiza  
dc.description.fil
Fil: Olaya, Astrid J.. Ecole Polytechnique Fédérale de Lausanne; Suiza  
dc.journal.title
Electrochimica Acta  
dc.relation.alternativeid
info:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/abs/pii/S0013468622003383  
dc.relation.alternativeid
info:eu-repo/semantics/altIdentifier/doi/https://doi.org/10.1016/j.electacta.2022.140166  

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