Artículo
Screening of Atrazine Distribution in Groundwater and Modeling of Leaching Potential to the Unconfined Aquifer in the Pampean Plain of Cordoba, Argentina
Lutri, Veronica Florencia
; Blarasin, Mónica Teresa; Matteoda, Edel Mara; Currell, Matthew James; Giacobone, Daniela Beatriz
; Bécher Quinodóz, Fátima Noelia
; Cabrera, Adriana Edith
Fecha de publicación:
06/2022
Editorial:
Springer
Revista:
Environmental Processes
ISSN:
2198-7491
e-ISSN:
2198-7505
Idioma:
Inglés
Tipo de recurso:
Artículo publicado
Clasificación temática:
Resumen
The objective of this study was to analyze atrazine (ATZ) spatial distribution in groundwater and present the factors related to its leaching potential in an area under intensive agricultural activity within the fluvio-Aeolian plain of the province of Córdoba, Argentina. Using tools such as soil and groundwater sampling and analysis, batch tests and numerical modeling, the variables that control the atrazine sorption and leaching potential were evaluated. The herbicide was detected in 14.7% of groundwater samples (0.14 to 1.26 μg L−1) becoming a leachable herbicide with moderate potential for groundwater pollution according to the calculated GUS (Groundwater Ubiquity Score) index. Hydrogeological characteristics influenced its distribution in the unconfined aquifer. Areas with a thin vadose zone (VZ) showed the highest atrazine levels, while the lithology of the vadose zone was also critical. In areas with a predominance of coarse-textured sediments (sands and gravels), low clay percentages and lower Koc, atrazine exhibits high mobility, which makes possible its transport to the unconfined aquifer at sites with a deep water table (≈25 m below surface). Herbicide spray application generally coincides with the rainy seasons, which contributes to high leaching rates. Numerical modeling indicated that transport of water and ATZ occurs both through micropores continuously, and macropores episodically. Groundwater has become a secondary environmental subsystem affected by the presence of ATZ due to advective, dispersive and reactive processes which allow its transport through the VZ. Even at relatively low concentrations, the presence of atrazine in groundwater requires long-term planning to monitor and control.
Palabras clave:
ATRAZINE TRANSPORT MODEL
,
GROUNDWATER POLLUTION
,
HYDROGEOLOGY
,
PAMPEAN PLAIN
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Licencia
Identificadores
Colecciones
Articulos(CCT - CORDOBA)
Articulos de CTRO.CIENTIFICO TECNOL.CONICET - CORDOBA
Articulos de CTRO.CIENTIFICO TECNOL.CONICET - CORDOBA
Citación
Lutri, Veronica Florencia; Blarasin, Mónica Teresa; Matteoda, Edel Mara; Currell, Matthew James; Giacobone, Daniela Beatriz; et al.; Screening of Atrazine Distribution in Groundwater and Modeling of Leaching Potential to the Unconfined Aquifer in the Pampean Plain of Cordoba, Argentina; Springer; Environmental Processes; 9; 2; 6-2022; 1-27
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