Artículo

Using experimental and computational approaches to probe an unusual carbon-carbon bond cleavage observed in the synthesis of benzimidazole: N -oxides

Politano, FabrizioIcon ; Sandoval, Arturo León; Uranga, Jorge GustavoIcon ; Bujan, Elba InesIcon ; Leadbeater, Nicholas E.
Fecha de publicación: 01/2021
Editorial: Royal Society of Chemistry
Revista: Organic & Biomolecular Chemistry
ISSN: 1477-0520
Idioma: Inglés
Tipo de recurso: Artículo publicado
Clasificación temática:

Resumen

Experimental and computational studies have been performed in order to investigate an unusual carbon-carbon bond cleavage that occurs in the preparation of certain benzimidazole N-oxides from anilines. The key factor determining the outcome of the reaction was found to be the substituents on the amine functionality of the aniline.
Palabras clave: Benzimidazole , N-oxides , DFT , Prediction
 
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info:eu-repo/semantics/openAccess Excepto donde se diga explícitamente, este item se publica bajo la siguiente descripción: Creative Commons Attribution-NonCommercial-ShareAlike 2.5 Unported (CC BY-NC-SA 2.5)
Identificadores
URI: http://hdl.handle.net/11336/186173
URL: https://pubs.rsc.org/en/content/articlelanding/2021/OB/D0OB01797C
DOI: https://doi.org/10.1039/D0OB01797C
Colecciones
Articulos(INFIQC)
Articulos de INST.DE INVESTIGACIONES EN FISICO- QUIMICA DE CORDOBA
Citación
Politano, Fabrizio; Sandoval, Arturo León; Uranga, Jorge Gustavo; Bujan, Elba Ines; Leadbeater, Nicholas E.; Using experimental and computational approaches to probe an unusual carbon-carbon bond cleavage observed in the synthesis of benzimidazole: N -oxides; Royal Society of Chemistry; Organic & Biomolecular Chemistry; 19; 1; 1-2021; 208-215
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