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dc.contributor.author
Prina, Ignacio
dc.contributor.author
Buljubasich Gentiletti, Lisandro
dc.contributor.author
Acosta, Rodolfo Héctor
dc.date.available
2023-01-26T12:57:49Z
dc.date.issued
2013-11
dc.identifier.citation
Prina, Ignacio; Buljubasich Gentiletti, Lisandro; Acosta, Rodolfo Héctor; High-Resolution hyperpolarized J -spectra with parahydrogen discrimination; American Chemical Society; Journal of Physical Chemistry Letters; 4; 22; 11-2013; 3924-3928
dc.identifier.issn
1948-7185
dc.identifier.uri
http://hdl.handle.net/11336/185726
dc.description.abstract
Parahydrogen-induced polarization (PHIP) has become a powerful tool not only to overcome the low intrinsic sensitivity of nuclear magnetic resonance (NMR) but also as a probe for catalytic reactions, as a contrast agent in magnetic resonance imaging (MRI), or in analytic chemistry. In complex systems, the antiphase signals coming from parahydrogen in a PASADENA (parahydrogen and synthesis allow dramatically enhanced nuclear alignment) experiment can be partially canceled by the presence of large thermally polarized signals. In the present work, we present a simple method to separate the thermal and hyperpolrized contributions by taking advantage of their very different evolution during a modified CPMG sequence. The separation is obtained in combination with a property of the fast Fourier transform algorithm (FFT). The technique is experimentally demonstrated for a mixture of hyperpolarized 1-hexene and a large amount of CH2Cl2.
dc.format
application/pdf
dc.language.iso
eng
dc.publisher
American Chemical Society
dc.rights
info:eu-repo/semantics/openAccess
dc.rights.uri
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.subject
CPMG
dc.subject
HYPERPOLARIZATION
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NMR SPECTROSCOPY
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PARAHYDROGEN
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PASADENA
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PHIP
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PULSE SEQUENCE
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SPIN ECHOES
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Física Atómica, Molecular y Química
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Ciencias Físicas
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CIENCIAS NATURALES Y EXACTAS
dc.title
High-Resolution hyperpolarized J -spectra with parahydrogen discrimination
dc.type
info:eu-repo/semantics/article
dc.type
info:ar-repo/semantics/artículo
dc.type
info:eu-repo/semantics/publishedVersion
dc.date.updated
2023-01-19T11:24:18Z
dc.journal.volume
4
dc.journal.number
22
dc.journal.pagination
3924-3928
dc.journal.pais
Estados Unidos
dc.description.fil
Fil: Prina, Ignacio. Universidad Nacional de Córdoba. Facultad de Matemática, Astronomía y Física; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Física Enrique Gaviola. Universidad Nacional de Córdoba. Instituto de Física Enrique Gaviola; Argentina
dc.description.fil
Fil: Buljubasich Gentiletti, Lisandro. Universidad Nacional de Córdoba. Facultad de Matemática, Astronomía y Física; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Física Enrique Gaviola. Universidad Nacional de Córdoba. Instituto de Física Enrique Gaviola; Argentina
dc.description.fil
Fil: Acosta, Rodolfo Héctor. Universidad Nacional de Córdoba. Facultad de Matemática, Astronomía y Física; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Física Enrique Gaviola. Universidad Nacional de Córdoba. Instituto de Física Enrique Gaviola; Argentina
dc.journal.title
Journal of Physical Chemistry Letters
dc.relation.alternativeid
info:eu-repo/semantics/altIdentifier/url/http://pubs.acs.org/doi/abs/10.1021/jz402078h
dc.relation.alternativeid
info:eu-repo/semantics/altIdentifier/doi/http://dx.doi.org/10.1021/jz402078h
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