Artículo

Synthesis and Structure of the Dimeric Copper(II) Complex Tetrakis[N-thiazol-2-yl-(4-methylphenyl)sulfonamidate]dicopper(II)

Cabaleiro, Santiago; Calvo, RafaelIcon ; Castro, Jesús; Garcia Vazquez, J. Arturo; Napolitano, Lia M. B.; Nascimento, Otaciro R.; Perez Lourido, Paulo; Romero, Jaime; Sousa, Antonio
Fecha de publicación: 12/2008
Editorial: Springer
Revista: Journal Of Chemical Crystallography
ISSN: 1074-1542
Idioma: Inglés
Tipo de recurso: Artículo publicado
Clasificación temática:

Resumen

The coordination chemistry of the ligand N-thiazol-2-yl-toluenesulfonamidate towards the copper(II) ion has been investigated using an electrochemical synthesis method. The X-ray structure of this complex was elucidated and is discussed. The compound crystallised in the monoclinic crystal system, P21/c space group with a = 17.3888(9), b = 16.3003(9), c = 18.3679(9) Å and β = 114.3640(10)°. Four bidentate sulfathiazolato anions bridge two metal centers in a paddle-wheel fashion, with the nitrogen atoms as donors to give a dimeric species with a Cu···Cu distance of 2.7859(5) Å.
Palabras clave: COORDINACIÓN QUÍMICA , COBRE(II) , ELECTROSÍNTESIS
 
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info:eu-repo/semantics/restrictedAccess Excepto donde se diga explícitamente, este item se publica bajo la siguiente descripción: Creative Commons Attribution-NonCommercial-ShareAlike 2.5 Unported (CC BY-NC-SA 2.5)
Identificadores
URI: http://hdl.handle.net/11336/18570
URL: https://link.springer.com/article/10.1007%2Fs10870-007-9303-9
DOI: http://dx.doi.org/10.1007/s10870-007-9303-9
Colecciones
Articulos(INTEC)
Articulos de INST.DE DES.TECNOL.PARA LA IND.QUIMICA (I)
Citación
Cabaleiro, Santiago; Calvo, Rafael; Castro, Jesús; Garcia Vazquez, J. Arturo; Napolitano, Lia M. B.; et al.; Synthesis and Structure of the Dimeric Copper(II) Complex Tetrakis[N-thiazol-2-yl-(4-methylphenyl)sulfonamidate]dicopper(II); Springer; Journal Of Chemical Crystallography; 38; 1; 12-2008; 71-75
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