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dc.contributor.author
Gruber, Alexandra
dc.contributor.author
Navarro, Lucila
dc.contributor.author
Klinger, Daniel
dc.date.available
2023-01-23T15:47:05Z
dc.date.issued
2019-12
dc.identifier.citation
Gruber, Alexandra; Navarro, Lucila; Klinger, Daniel; Reactive Precursor Particles as Synthetic Platform for the Generation of Functional Nanoparticles, Nanogels, and Microgels; Wiley-VCH; Advanced Materials Interfaces; 7; 5; 12-2019; 1-33
dc.identifier.issn
2196-7350
dc.identifier.uri
http://hdl.handle.net/11336/185293
dc.description.abstract
Precise control of the chemical functionality of polymer nanoparticles is a key requirement in tailoring their (dynamic) colloidal properties toward advanced applications. However, current synthetic techniques are still limited in the versatility of chemical design and preparation of such functional colloidal nanomaterials. Two major challenges remain: First, various particle preparation methods are restricted in their functional group tolerance, thus hindering certain combinations of polymer backbones with specific functional groups. Second, the preparation of particles with different functionalities requires the synthesis of different particle batches. But this often results in a simultaneous variation of colloidal features. As a result, the accurate determination of important structure–property relations is still hindered. To address these restrictions, postmodification of preformed reactive particles is gaining more attention. This technique has evolved from polymer synthesis, where postpolymerization functionalization enables the introduction of a plethora of functional groups without changing the degree of polymerization and the molecular weight distribution. Similarly, modifying precursor particles enables the introduction of functional groups into particles while reducing variations in colloidal features, e.g., particle size and size distribution. This powerful synthetic method complements established procedures for functionalization of particle surfaces, thereby enabling the facile preparation of (multi-)functional particle libraries, which will allow precise investigations of structure–property relations.
dc.format
application/pdf
dc.language.iso
eng
dc.publisher
Wiley-VCH
dc.rights
info:eu-repo/semantics/openAccess
dc.rights.uri
https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
dc.subject
CLICK CHEMISTRY
dc.subject
FUNCTIONAL NANOPARTICLE LIBRARIES
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PARTICLE ANALOGOUS REACTION
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POSTFUNCTIONALIZATION
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STRUCTURE–PROPERTY RELATIONS
dc.subject.classification
Ingeniería de los Materiales
dc.subject.classification
Ingeniería de los Materiales
dc.subject.classification
INGENIERÍAS Y TECNOLOGÍAS
dc.title
Reactive Precursor Particles as Synthetic Platform for the Generation of Functional Nanoparticles, Nanogels, and Microgels
dc.type
info:eu-repo/semantics/article
dc.type
info:ar-repo/semantics/artículo
dc.type
info:eu-repo/semantics/publishedVersion
dc.date.updated
2023-01-23T00:37:02Z
dc.journal.volume
7
dc.journal.number
5
dc.journal.pagination
1-33
dc.journal.pais
Alemania
dc.journal.ciudad
Berlín
dc.description.fil
Fil: Gruber, Alexandra. Freie Universität Berlin; Alemania
dc.description.fil
Fil: Navarro, Lucila. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Desarrollo Tecnológico para la Industria Química. Universidad Nacional del Litoral. Instituto de Desarrollo Tecnológico para la Industria Química; Argentina. Freie Universität Berlin; Alemania
dc.description.fil
Fil: Klinger, Daniel. Freie Universität Berlin; Alemania
dc.journal.title
Advanced Materials Interfaces
dc.relation.alternativeid
info:eu-repo/semantics/altIdentifier/url/https://onlinelibrary.wiley.com/doi/full/10.1002/admi.201901676
dc.relation.alternativeid
info:eu-repo/semantics/altIdentifier/doi/https://doi.org/10.1002/admi.201901676
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