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dc.contributor.author
Gavilán Arriazu, Edgardo Maximiliano  
dc.contributor.author
Barraco Diaz, Daniel Eugenio  
dc.contributor.author
Leiva, Ezequiel Pedro M.  
dc.date.available
2023-01-09T20:10:13Z  
dc.date.issued
2021-11-08  
dc.identifier.citation
Gavilán Arriazu, Edgardo Maximiliano; Barraco Diaz, Daniel Eugenio; Leiva, Ezequiel Pedro M.; On how interactions influence kinetic limitations in alkali-ion batteries. Application to Li-ion intercalation into graphite through voltammetric experiments; Springer; Journal of Solid State Electrochemistry (print); 25; 12; 8-11-2021; 2793-2806  
dc.identifier.issn
1432-8488  
dc.identifier.uri
http://hdl.handle.net/11336/184011  
dc.description.abstract
Here, we report on a novel study for battery application regarding the impact of interactions in charge transfer and diffusional features in finite-size systems. An easy way to represent these features is the construction of a map called zone diagram for voltammetry simulations, where different domains are related with a characteristic charge transfer-diffusional limitation. This is particularly relevant for alkali-ion intercalation into hosts, since interactions between inserted ions have demonstrated to have a strong influence on the electrochemical behaviour of these systems. The Frumkin isotherm is used here as a general model to understand the simplest scenarios, which introduces interactions between inserted particles in their thermodynamic descriptions. We show how the impact of these interactions becomes more evident for systems that present a reversible charge transfer. On the contrary, for irreversible reactions, features tend to become independent of interactions. Finally, we apply the methodology to understand some features of Li-ion intercalation in graphite films. It comes out that for this system, a surface wave (adsorption like) behaviour could only be reached in experiments lasting more than a year. This explains the large hysteresis found in experiments. We also constructed a sweep rate-film thickness zone diagram, to present the results in a more straightforward fashion to experimentalists.  
dc.format
application/pdf  
dc.language.iso
eng  
dc.publisher
Springer  
dc.rights
info:eu-repo/semantics/restrictedAccess  
dc.rights.uri
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/  
dc.subject
ALKALI-ION BATTERY  
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LITHIUM-ION BATTERY  
dc.subject
VOLTAMMETRY  
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GRAPHITE  
dc.subject.classification
Físico-Química, Ciencia de los Polímeros, Electroquímica  
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Ciencias Químicas  
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CIENCIAS NATURALES Y EXACTAS  
dc.title
On how interactions influence kinetic limitations in alkali-ion batteries. Application to Li-ion intercalation into graphite through voltammetric experiments  
dc.type
info:eu-repo/semantics/article  
dc.type
info:ar-repo/semantics/artículo  
dc.type
info:eu-repo/semantics/publishedVersion  
dc.date.updated
2022-09-22T10:32:38Z  
dc.identifier.eissn
1433-0768  
dc.journal.volume
25  
dc.journal.number
12  
dc.journal.pagination
2793-2806  
dc.journal.pais
Alemania  
dc.description.fil
Fil: Gavilán Arriazu, Edgardo Maximiliano. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Física Enrique Gaviola. Universidad Nacional de Córdoba. Instituto de Física Enrique Gaviola; Argentina  
dc.description.fil
Fil: Barraco Diaz, Daniel Eugenio. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Física Enrique Gaviola. Universidad Nacional de Córdoba. Instituto de Física Enrique Gaviola; Argentina  
dc.description.fil
Fil: Leiva, Ezequiel Pedro M.. Universidad Nacional de Córdoba. Facultad de Cs.químicas. Departamento de Química Teórica y Computacional; Argentina  
dc.journal.title
Journal of Solid State Electrochemistry (print)  
dc.relation.alternativeid
info:eu-repo/semantics/altIdentifier/url/https://link.springer.com/10.1007/s10008-021-05079-6  
dc.relation.alternativeid
info:eu-repo/semantics/altIdentifier/doi/http://dx.doi.org/10.1007/s10008-021-05079-6