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dc.contributor.author
Picone, Andrea Lorena
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dc.contributor.author
Warrender, Stewart J.
dc.contributor.author
Slawin, Alexandra M. Z.
dc.contributor.author
Dawson, Daniel M.
dc.contributor.author
Ashbrook, Sharon E.
dc.contributor.author
Wright, Paul A.
dc.contributor.author
Thompson, Stephen P.
dc.contributor.author
Gaberova, Lucia
dc.contributor.author
Llewellyn, Philip L.
dc.contributor.author
Moulin, Beatrice
dc.contributor.author
Vimont, Alexandre
dc.contributor.author
Daturi, Marco
dc.contributor.author
Bum Park, Min
dc.contributor.author
Kyung Sung, Sam
dc.contributor.author
Nam, In-Sik
dc.contributor.author
Bong Hong, Suk
dc.date.available
2022-12-22T16:45:48Z
dc.date.issued
2011-12
dc.identifier.citation
Picone, Andrea Lorena; Warrender, Stewart J.; Slawin, Alexandra M. Z.; Dawson, Daniel M.; Ashbrook, Sharon E.; et al.; A co-templating route to the synthesis of Cu SAPO STA-7, giving an active catalyst for the selective catalytic reduction of NO; Elsevier Science; Microporous and Mesoporous Materials; 146; 1-3; 12-2011; 36-47
dc.identifier.issn
1387-1811
dc.identifier.uri
http://hdl.handle.net/11336/182229
dc.description.abstract
Copper cyclam (cyclam = 1,4,8,11-tetraazacyclotetradecane) and tetraethylammonium (TEA+ ) act as cotemplates for the hydrothermal crystallisation of the silicoaluminophosphate SAPO STA-7, as determined by UV–visible, ESR and solid-state MAS NMR spectroscopies, powder and single crystal X-ray diffraction and chemical analysis. Calcination of the as-prepared solid in flowing oxygen removes all organics to leave Cu(II),H-SAPO STA-7 (hereafter Cu-SAPO STA-7) in which the presence of bridging hydroxyl groups is confirmed by IR and the presence of multiple environments for Cu2+ is shown by IR using NO as a probe molecule. Rietveld analysis of synchrotron X-ray powder diffraction data collected over the temperature range 293–673 K locates Cu2+ cations distributed over four sites: above six membered rings (6MRs) and in the three different 8MR windows of the STA-7 structure. Cu-SAPO STA-7 is a very good catalyst for the selective catalytic reduction of NO with NH3, in the presence or absence of water vapour, so that this approach represents an efficient and effective route to copper-containing SAPO catalysts that obviates the need for an aqueous Cu2+ ion exchange step during preparation.
dc.format
application/pdf
dc.language.iso
eng
dc.publisher
Elsevier Science
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dc.rights
info:eu-repo/semantics/openAccess
dc.rights.uri
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.subject
MICROPOROUS SILICOALUMINOPHOSPHATE
dc.subject
COPPER CYCLAM CO-TEMPLATE Cu SAPO STA-7
dc.subject
STRUCTURE ANALYSIS
dc.subject
SELECTIVE CATALYTIC REDUCTION NO
dc.subject.classification
Otras Ciencias Químicas
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dc.subject.classification
Ciencias Químicas
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dc.subject.classification
CIENCIAS NATURALES Y EXACTAS
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dc.title
A co-templating route to the synthesis of Cu SAPO STA-7, giving an active catalyst for the selective catalytic reduction of NO
dc.type
info:eu-repo/semantics/article
dc.type
info:ar-repo/semantics/artículo
dc.type
info:eu-repo/semantics/publishedVersion
dc.date.updated
2022-07-04T19:45:24Z
dc.journal.volume
146
dc.journal.number
1-3
dc.journal.pagination
36-47
dc.journal.pais
Países Bajos
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dc.journal.ciudad
Amsterdam
dc.description.fil
Fil: Picone, Andrea Lorena. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata; Argentina. University of St. Andrews; Reino Unido
dc.description.fil
Fil: Warrender, Stewart J.. University of St. Andrews; Reino Unido
dc.description.fil
Fil: Slawin, Alexandra M. Z.. University of St. Andrews; Reino Unido
dc.description.fil
Fil: Dawson, Daniel M.. University of St. Andrews; Reino Unido
dc.description.fil
Fil: Ashbrook, Sharon E.. University of St. Andrews; Reino Unido
dc.description.fil
Fil: Wright, Paul A.. University of St. Andrews; Reino Unido
dc.description.fil
Fil: Thompson, Stephen P.. Harwell Science and Innovation Campus; Reino Unido
dc.description.fil
Fil: Gaberova, Lucia. Aix-Marseille Université; Mónaco
dc.description.fil
Fil: Llewellyn, Philip L.. Aix-Marseille Université; Mónaco
dc.description.fil
Fil: Moulin, Beatrice. Universite de Caen Basse Normandie; Francia
dc.description.fil
Fil: Vimont, Alexandre. Universite de Caen Basse Normandie; Francia
dc.description.fil
Fil: Daturi, Marco. Universite de Caen Basse Normandie; Francia
dc.description.fil
Fil: Bum Park, Min. Universite de Caen Basse Normandie; Francia
dc.description.fil
Fil: Kyung Sung, Sam. Pohang University of Science and Technology; Corea del Sur
dc.description.fil
Fil: Nam, In-Sik. Pohang University of Science and Technology; Corea del Sur
dc.description.fil
Fil: Bong Hong, Suk. Pohang University of Science and Technology; Corea del Sur
dc.journal.title
Microporous and Mesoporous Materials
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dc.relation.alternativeid
info:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/pii/S1387181111002083
dc.relation.alternativeid
info:eu-repo/semantics/altIdentifier/doi/http://dx.doi.org/10.1016/j.micromeso.2011.04.039
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