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dc.contributor.author
Xu, Yixin
dc.contributor.author
Dorneles de Mello, Matheus
dc.contributor.author
Zhou, Chen
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Sharma, Shruti
dc.contributor.author
Karagoz, Burcu
dc.contributor.author
Head, Ashley R.
dc.contributor.author
Darbari, Zubin
dc.contributor.author
Waluyo, Iradwikanari
dc.contributor.author
Hunt, Adrian
dc.contributor.author
Stacchiola, Dario Jose
dc.contributor.author
Manzi, Sergio Javier
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Boscoboinik, Alejandro Miguel
dc.contributor.author
Pereyra, Victor Daniel
dc.contributor.author
Boscoboinik, J. Anibal
dc.date.available
2022-10-17T14:00:45Z
dc.date.issued
2021-10
dc.identifier.citation
Xu, Yixin; Dorneles de Mello, Matheus; Zhou, Chen; Sharma, Shruti; Karagoz, Burcu; et al.; Xenon Trapping in Metal-Supported Silica Nanocages; Wiley VCH Verlag; Small; 17; 39; 10-2021; 1-10
dc.identifier.issn
1613-6810
dc.identifier.uri
http://hdl.handle.net/11336/173462
dc.description.abstract
Xenon (Xe) is a valuable and scarce noble gas used in various applications, including lighting, electronics, and anesthetics, among many others. It is also a volatile byproduct of the nuclear fission of uranium. A novel material architecture consisting of silicate nanocages in contact with a metal surface and an approach for trapping single Xe atoms in these cages is presented. The trapping is done at low Xe pressures and temperatures between 400 and 600 K, and the process is monitored in situ using synchrotron-based ambient pressure X-ray photoelectron spectroscopy. Release of the Xe from the cages occurs only when heating to temperatures above 750 K. A model that explains the experimental trapping kinetics is proposed and tested using Monte Carlo methods. Density functional theory calculations show activation energies for Xe exiting the cages consistent with experiments. This work can have significant implications in various fields, including Xe production, nuclear power, nuclear waste remediation, and nonproliferation of nuclear weapons. The results are also expected to apply to argon, krypton, and radon, opening an even more comprehensive range of applications.
dc.format
application/pdf
dc.language.iso
eng
dc.publisher
Wiley VCH Verlag
dc.rights
info:eu-repo/semantics/restrictedAccess
dc.rights.uri
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.subject
DFT CALCULATION
dc.subject
MONTE CARLO SIMULATION
dc.subject
SILICA NANOCAGE
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SYNCHROTRON AP-XPS
dc.subject
XENON TRAPPING
dc.subject.classification
Otras Ciencias Físicas
dc.subject.classification
Ciencias Físicas
dc.subject.classification
CIENCIAS NATURALES Y EXACTAS
dc.title
Xenon Trapping in Metal-Supported Silica Nanocages
dc.type
info:eu-repo/semantics/article
dc.type
info:ar-repo/semantics/artículo
dc.type
info:eu-repo/semantics/publishedVersion
dc.date.updated
2022-09-20T15:46:47Z
dc.identifier.eissn
1613-6829
dc.journal.volume
17
dc.journal.number
39
dc.journal.pagination
1-10
dc.journal.pais
Alemania
dc.journal.ciudad
Weinheim
dc.description.fil
Fil: Xu, Yixin. Brookhaven National Laboratory; Estados Unidos. State University of New York. Stony Brook University; Estados Unidos
dc.description.fil
Fil: Dorneles de Mello, Matheus. University Of Delaware; Estados Unidos. Brookhaven National Laboratory; Estados Unidos
dc.description.fil
Fil: Zhou, Chen. Brookhaven National Laboratory; Estados Unidos. State University of New York. Stony Brook University; Estados Unidos
dc.description.fil
Fil: Sharma, Shruti. State University of New York. Stony Brook University; Estados Unidos
dc.description.fil
Fil: Karagoz, Burcu. Brookhaven National Laboratory; Estados Unidos
dc.description.fil
Fil: Head, Ashley R.. Brookhaven National Laboratory; Estados Unidos
dc.description.fil
Fil: Darbari, Zubin. State University of New York. Stony Brook University; Estados Unidos. Brookhaven National Laboratory; Estados Unidos
dc.description.fil
Fil: Waluyo, Iradwikanari. Brookhaven National Laboratory; Estados Unidos
dc.description.fil
Fil: Hunt, Adrian. Brookhaven National Laboratory; Estados Unidos
dc.description.fil
Fil: Stacchiola, Dario Jose. Brookhaven National Laboratory; Estados Unidos
dc.description.fil
Fil: Manzi, Sergio Javier. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - San Luis. Instituto de Física Aplicada "Dr. Jorge Andrés Zgrablich". Universidad Nacional de San Luis. Facultad de Ciencias Físico Matemáticas y Naturales. Instituto de Física Aplicada "Dr. Jorge Andrés Zgrablich"; Argentina
dc.description.fil
Fil: Boscoboinik, Alejandro Miguel. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. University of Pennsylvania; Estados Unidos
dc.description.fil
Fil: Pereyra, Victor Daniel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - San Luis. Instituto de Matemática Aplicada de San Luis "Prof. Ezio Marchi". Universidad Nacional de San Luis. Facultad de Ciencias Físico, Matemáticas y Naturales. Instituto de Matemática Aplicada de San Luis "Prof. Ezio Marchi"; Argentina
dc.description.fil
Fil: Boscoboinik, J. Anibal. University Of Delaware; Estados Unidos. Brookhaven National Laboratory; Estados Unidos. State University of New York. Stony Brook University; Estados Unidos
dc.journal.title
Small
dc.relation.alternativeid
info:eu-repo/semantics/altIdentifier/doi/http://dx.doi.org/10.1002/smll.202103661
dc.relation.alternativeid
info:eu-repo/semantics/altIdentifier/url/https://onlinelibrary.wiley.com/doi/10.1002/smll.202103661
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