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dc.contributor.author
Colli, Alejandro Nicolás
dc.contributor.author
Bisang, Jose Maria
dc.date.available
2017-06-01T19:56:58Z
dc.date.issued
2015-02
dc.identifier.citation
Colli, Alejandro Nicolás; Bisang, Jose Maria; Comparison of the performance of flow-by three-dimensional cylindrical electrochemical reactors with inner or outer counter electrode under limiting current conditions; Elsevier; Electrochimica Acta; 154; 2-2015; 468-475
dc.identifier.issn
0013-4686
dc.identifier.uri
http://hdl.handle.net/11336/17308
dc.description.abstract
The influence of the position of the counter electrode on the behaviour of a cylindrical electrochemical reactor with a three-dimensional electrode in flow-by configuration is analysed. Experimental results of the potential distribution are compared with theoretical predictions obtaining a close agreement between them. The best performance was observed for the arrangement with an outer counter electrode, where the largest bed thickness is obtained for a given potential difference in the three-dimensional structure; which, under limiting current conditions, tolerates a higher current increasing the conversion per pass. The reactor was also checked for the removal of copper from dilute solutions and the experimental results coincide with the theoretical predictions. The morphology of the electrodeposited copper is discussed as a function of the radial position inside the three-dimensional structure.
dc.format
application/pdf
dc.language.iso
eng
dc.publisher
Elsevier
dc.rights
info:eu-repo/semantics/restrictedAccess
dc.rights.uri
https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
dc.subject
Electrochemical Reactors
dc.subject
Mass-Transfer Coefficient
dc.subject
Metal Removal
dc.subject
Potential Distribution
dc.subject
Three-Dimensional Electrodes
dc.subject.classification
Otras Ingeniería Química
dc.subject.classification
Ingeniería Química
dc.subject.classification
INGENIERÍAS Y TECNOLOGÍAS
dc.title
Comparison of the performance of flow-by three-dimensional cylindrical electrochemical reactors with inner or outer counter electrode under limiting current conditions
dc.type
info:eu-repo/semantics/article
dc.type
info:ar-repo/semantics/artículo
dc.type
info:eu-repo/semantics/publishedVersion
dc.date.updated
2017-05-04T18:43:06Z
dc.journal.volume
154
dc.journal.pagination
468-475
dc.journal.pais
Países Bajos
dc.journal.ciudad
Amsterdam
dc.description.fil
Fil: Colli, Alejandro Nicolás. Universidad Nacional del Litoral. Facultad de Ingeniería Química. Programa de Electroquímica Aplicada E Ingeniería Electroquímica; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe; Argentina
dc.description.fil
Fil: Bisang, Jose Maria. Universidad Nacional del Litoral. Facultad de Ingeniería Química. Programa de Electroquímica Aplicada E Ingeniería Electroquímica; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe; Argentina
dc.journal.title
Electrochimica Acta
dc.relation.alternativeid
info:eu-repo/semantics/altIdentifier/doi/http://dx.doi.org/10.1016/j.electacta.2014.12.076
dc.relation.alternativeid
info:eu-repo/semantics/altIdentifier/url/http://www.sciencedirect.com/science/article/pii/S0013468614025237


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