Artículo

Polymerization kinetics and microstructure of waterborne acrylic/alkyd nanocomposites synthesized by miniemulsion

Goikoetxea, Monika; Minari, Roque JavierIcon ; Beristain, Itxaso; Paulis, María; Barandiaran, María J.; Asua, José M.
Fecha de publicación: 08/2009
Editorial: John Wiley & Sons Inc
Revista: Journal Of Polymer Science Part A: Polymer Chemistry
ISSN: 0887-624X
Idioma: Inglés
Tipo de recurso: Artículo publicado
Clasificación temática:

Resumen

Waterborne acrylic-alkyd nanocomposites are expected to combine the positive properties of alkyd resins and acrylic polymers. In this work the kinetics of the miniemulsion polymerization used to synthesize these nanocomposites and the effect of the process variables on the polymer architecture and particle morphology was investigated. It was found that resin hydrophobicity and the type of initiator strongly affected the microstructure of these materials. The mechanisms responsible for these effects were discussed.
Palabras clave: Coatings , Composites , Miniemulsion Polymerization , Alkyds
 
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info:eu-repo/semantics/openAccess Excepto donde se diga explícitamente, este item se publica bajo la siguiente descripción: Creative Commons Attribution-NonCommercial-ShareAlike 2.5 Unported (CC BY-NC-SA 2.5)
Identificadores
URI: http://hdl.handle.net/11336/17111
DOI: http://dx.doi.org/10.1002/pola.23535
URL: http://onlinelibrary.wiley.com/doi/10.1002/pola.23535/abstract
Colecciones
Articulos(INTEC)
Articulos de INST.DE DES.TECNOL.PARA LA IND.QUIMICA (I)
Citación
Goikoetxea, Monika; Minari, Roque Javier; Beristain, Itxaso; Paulis, María; Barandiaran, María J.; et al.; Polymerization kinetics and microstructure of waterborne acrylic/alkyd nanocomposites synthesized by miniemulsion; John Wiley & Sons Inc; Journal Of Polymer Science Part A: Polymer Chemistry; 47; 19; 8-2009; 4871-4885
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