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dc.contributor.author
Minari, Roque Javier  
dc.contributor.author
Goikoetxea, Monika  
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Beristain, Itxaso  
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Paulis, María  
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Barandiaran, María J.  
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Asua, José M.  
dc.date.available
2017-05-30T18:59:14Z  
dc.date.issued
2009-05  
dc.identifier.citation
Minari, Roque Javier; Goikoetxea, Monika; Beristain, Itxaso; Paulis, María; Barandiaran, María J.; et al.; Molecular Characterization of Alkyd/Acrylic Latexes Prepared by Miniemulsion Polymerization; John Wiley & Sons Inc; Journal Of Applied Polymer Science; 114; 5; 5-2009; 3143-3151  
dc.identifier.issn
0021-8995  
dc.identifier.uri
http://hdl.handle.net/11336/17109  
dc.description.abstract
The molecular characterization of alkyd/ acrylic hybrid latexes produced by miniemulsion polymerization was characterized in terms of the resin degree of grafting, acrylic degree of grafting, reacted double bonds in the alkyd, gel content, and molecular weight distribution of the sol part. A simple method based on conventional size exclusion chromatography measurements was developed to estimate the fraction of alkyd resin grafted to the acrylic polymer. The method could be applied to completely soluble hybrids and to hybrids containing gel. Also, the limits of the extraction method used in the literature to estimate the fraction of acrylic polymer grafted to the alkyd was investigated; we found that this technique only provided accurate results at high values of the acrylic degree of grafting. The combination of this information with the reacted double bonds of the alkyd (determined by iodine titration) and the molecular weight distribution of the sol polymer provided a detailed characterization of the alkyd–acrylic hybrid polymer.  
dc.format
application/pdf  
dc.language.iso
eng  
dc.publisher
John Wiley & Sons Inc  
dc.rights
info:eu-repo/semantics/openAccess  
dc.rights.uri
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/  
dc.subject
Coatings  
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Composites  
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Emulsion Polymerization  
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Nano-materiales  
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Nanotecnología  
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INGENIERÍAS Y TECNOLOGÍAS  
dc.title
Molecular Characterization of Alkyd/Acrylic Latexes Prepared by Miniemulsion Polymerization  
dc.type
info:eu-repo/semantics/article  
dc.type
info:ar-repo/semantics/artículo  
dc.type
info:eu-repo/semantics/publishedVersion  
dc.date.updated
2017-05-22T14:03:37Z  
dc.journal.volume
114  
dc.journal.number
5  
dc.journal.pagination
3143-3151  
dc.journal.pais
Estados Unidos  
dc.journal.ciudad
Hoboken  
dc.description.fil
Fil: Minari, Roque Javier. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Desarrollo Tecnológico para la Industria Química. Universidad Nacional del Litoral. Instituto de Desarrollo Tecnológico para la Industria Química; Argentina  
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Fil: Goikoetxea, Monika. Universidad del País Vasco; España  
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Fil: Beristain, Itxaso. Universidad del País Vasco; España  
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Fil: Paulis, María. Universidad del País Vasco; España  
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Fil: Barandiaran, María J.. Universidad del País Vasco; España  
dc.description.fil
Fil: Asua, José M.. Universidad del País Vasco; España  
dc.journal.title
Journal Of Applied Polymer Science  
dc.relation.alternativeid
info:eu-repo/semantics/altIdentifier/doi/http://dx.doi.org/10.1002/app.30866  
dc.relation.alternativeid
info:eu-repo/semantics/altIdentifier/url/http://onlinelibrary.wiley.com/doi/10.1002/app.30866/abstract