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dc.contributor.author
Díaz, Jimena Estela  
dc.contributor.author
Gruber, Nadia  
dc.contributor.author
Lunazzi, Lodovico  
dc.contributor.author
Mazzanti, Andrea  
dc.contributor.author
Orelli, Liliana Raquel  
dc.date.available
2017-05-22T20:08:28Z  
dc.date.issued
2011-11  
dc.identifier.citation
Díaz, Jimena Estela; Gruber, Nadia; Lunazzi, Lodovico; Mazzanti, Andrea; Orelli, Liliana Raquel; Conformation and stereodynamics of 1,2-diaryltetrahydropyrimidine and of its five- and seven-membered ring analogs; Elsevier; Tetrahedron; 67; 47; 11-2011; 9129-9133  
dc.identifier.issn
0040-4020  
dc.identifier.uri
http://hdl.handle.net/11336/16828  
dc.description.abstract
The 1-(2-nitrophenyl)-2-(2-methylphenyl)-1,4,5,6-tetrahydropyrimidine and its five- and seven-membered ring analogs were synthesized and their conformational properties investigated by low temperature NMR spectroscopy and DFT theoretical calculations. Restricted rotation of the aryl substituents were observed in all cases and the corresponding barriers determined. In the case of the six-membered ring derivative the additional conformers resulting from a ring inversion process were also detected.  
dc.format
application/pdf  
dc.language.iso
eng  
dc.publisher
Elsevier  
dc.rights
info:eu-repo/semantics/openAccess  
dc.rights.uri
https://creativecommons.org/licenses/by-nc-nd/2.5/ar/  
dc.subject
Nitrogen Heterocycles  
dc.subject
Conformational Analysis  
dc.subject
Axial Chirality  
dc.subject
Dynamic Nmr  
dc.subject
Dft Calculations  
dc.subject.classification
Química Orgánica  
dc.subject.classification
Ciencias Químicas  
dc.subject.classification
CIENCIAS NATURALES Y EXACTAS  
dc.title
Conformation and stereodynamics of 1,2-diaryltetrahydropyrimidine and of its five- and seven-membered ring analogs  
dc.type
info:eu-repo/semantics/article  
dc.type
info:ar-repo/semantics/artículo  
dc.type
info:eu-repo/semantics/publishedVersion  
dc.date.updated
2017-02-15T14:09:59Z  
dc.journal.volume
67  
dc.journal.number
47  
dc.journal.pagination
9129-9133  
dc.journal.pais
Países Bajos  
dc.journal.ciudad
Ámsterdam  
dc.description.fil
Fil: Díaz, Jimena Estela. Universidad de Buenos Aires. Facultad de Farmacia y Bioquímica. Departamento de Química Orgánica; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina  
dc.description.fil
Fil: Gruber, Nadia. Universidad de Buenos Aires. Facultad de Farmacia y Bioquímica. Departamento de Química Orgánica; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina  
dc.description.fil
Fil: Lunazzi, Lodovico. Universita Di Bologna; Italia  
dc.description.fil
Fil: Mazzanti, Andrea. Universita Di Bologna; Italia  
dc.description.fil
Fil: Orelli, Liliana Raquel. Universidad de Buenos Aires. Facultad de Farmacia y Bioquímica. Departamento de Química Orgánica; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina  
dc.journal.title
Tetrahedron  
dc.relation.alternativeid
info:eu-repo/semantics/altIdentifier/url/http://www.sciencedirect.com/science/article/pii/S004040201101461X  
dc.relation.alternativeid
info:eu-repo/semantics/altIdentifier/doi/http://dx.doi.org/10.1016/j.tet.2011.09.091  

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