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Artículo

Synthesis and spectroscopic 27Al NMR and Raman characterization of new materials based on the assembly of [AlO4Al12(OH)24(H2O)12] 7þ isopolycation and Co–Cr and [AlMo6O24H6] 3- Anderson heteropolyanions

Muñoz, MercedesIcon ; Cabello, Carmen Ines; Botto, Irma LiaIcon ; Minelli, Giuliano; Capron, Mickael; Lamonier, Carole; Payen, Edmond
Fecha de publicación: 30/09/2007
Editorial: Elsevier Science
Revista: Journal Of Molecular Structure
ISSN: 0022-2860
Idioma: Inglés
Tipo de recurso: Artículo publicado
Clasificación temática:
Ingeniería Química

Resumen

New advanced inorganic composite materials were prepared by combination of the polycation [AlO4Al12(OH)24(H2O)12]7+ with heteropolyoxomolybdates of Anderson type structure with formula: [XMo6O24H6]3- where X=Al(III), Co(III), and Cr(III). The synthesis of these materials is performed by direct mixture of the isopolycation and heteropolyanions in a pH controlled aqueous solution. These new materials were characterized by X-ray powder diffraction (XRD), 27Al nuclear magnetic resonance (NMR); vibrational (FT-IR and Raman Microprobe) and UV–visible diffuse reflectance (UV–vis-DR) spectroscopies and their stability was studied by thermal analysis (TG-DTA). The NMR and Raman spectroscopies are useful to characterize these materials and to demonstrate that the Anderson structure in the composite lattice is preserved. Likewise, XRD, Raman microprobe and UV–vis-DR spectroscopic techniques achieve the further characterization of thermal residues or intermediates. All results allow us to suggest that the evolution of properties depends on the heteroatom nature in the Anderson structural units of these new materials.
Palabras clave: Heteropolyanions , Inorganic Composites , Al13-Isopolycation , 27al Mas Nmr , Raman Microprobe , Oxidative Desulfurization , Hydrotreatment Catalysts
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info:eu-repo/semantics/openAccess Excepto donde se diga explícitamente, este item se publica bajo la siguiente descripción: Atribución-NoComercial-SinDerivadas 2.5 Argentina (CC BY-NC-ND 2.5 AR)
Identificadores
URI: http://hdl.handle.net/11336/16750
DOI: http://dx.doi.org/10.1016/j.molstruc.2006.11.067
URL: http://www.sciencedirect.com/science/article/pii/S0022286006009495
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Articulos de CENTRO DE INV EN CS.APLICADAS "DR.JORGE J.RONCO"
Citación
Muñoz, Mercedes; Cabello, Carmen Ines; Botto, Irma Lia; Minelli, Giuliano; Capron, Mickael; et al.; Synthesis and spectroscopic 27Al NMR and Raman characterization of new materials based on the assembly of [AlO4Al12(OH)24(H2O)12] 7þ isopolycation and Co–Cr and [AlMo6O24H6] 3- Anderson heteropolyanions; Elsevier Science; Journal Of Molecular Structure; 841; 1-3; 30-9-2007; 96-103
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