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dc.contributor.author
Riccardo, Jose Luis  
dc.contributor.author
Romá, Federico José  
dc.contributor.author
Ramirez Pastor, Antonio Jose  
dc.date.available
2022-05-27T12:47:09Z  
dc.date.issued
2005-12  
dc.identifier.citation
Riccardo, Jose Luis; Romá, Federico José; Ramirez Pastor, Antonio Jose; Generalized statistical description of adsorption of polyatomics; Elsevier Science; Applied Surface Science; 252; 3; 12-2005; 505-511  
dc.identifier.issn
0169-4332  
dc.identifier.uri
http://hdl.handle.net/11336/158338  
dc.description.abstract
Multisite-occupancy adsorption is described as a fractional statistic problem, based on Haldane’s statistics. Site exclusion is characterized by a statistical exclusion parameter, g, which relates to the molecular size and lattice geometry. A general adsorption isotherm is obtained and comparisons with experiments indicate that the spatial configuration of adsorbed molecules and lateral interactions may accurately be assessed from this theory. In addition, the theoretical framework developed in this paper allows to describe orientational transitions occurring in adlayers of polyatomics.  
dc.format
application/pdf  
dc.language.iso
eng  
dc.publisher
Elsevier Science  
dc.rights
info:eu-repo/semantics/openAccess  
dc.rights.uri
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/  
dc.subject
ADSORPTION ISOTHERMS  
dc.subject
MULTISITE OCCUPANCY  
dc.subject
QUANTUM FRACTIONAL STATISTICS  
dc.subject
MONTE CARLO SIMULATIONS  
dc.subject
EQUILIBRIUM THERMODYNAMICS AND STATISTICAL MECHANICS  
dc.subject.classification
Física de los Materiales Condensados  
dc.subject.classification
Ciencias Físicas  
dc.subject.classification
CIENCIAS NATURALES Y EXACTAS  
dc.title
Generalized statistical description of adsorption of polyatomics  
dc.type
info:eu-repo/semantics/article  
dc.type
info:ar-repo/semantics/artículo  
dc.type
info:eu-repo/semantics/publishedVersion  
dc.date.updated
2022-05-20T15:06:54Z  
dc.journal.volume
252  
dc.journal.number
3  
dc.journal.pagination
505-511  
dc.journal.pais
Países Bajos  
dc.journal.ciudad
Amsterdam  
dc.description.fil
Fil: Riccardo, Jose Luis. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - San Luis; Argentina. Universidad Nacional de San Luis. Facultad de Cs.fisico Matemáticas y Naturales. Laboratorio de Cs.de Superficies y Medios Porosos; Argentina  
dc.description.fil
Fil: Romá, Federico José. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - San Luis; Argentina. Universidad Nacional de San Luis. Facultad de Cs.fisico Matemáticas y Naturales. Laboratorio de Cs.de Superficies y Medios Porosos; Argentina  
dc.description.fil
Fil: Ramirez Pastor, Antonio Jose. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - San Luis; Argentina. Universidad Nacional de San Luis. Facultad de Cs.fisico Matemáticas y Naturales. Laboratorio de Cs.de Superficies y Medios Porosos; Argentina  
dc.journal.title
Applied Surface Science  
dc.relation.alternativeid
info:eu-repo/semantics/altIdentifier/doi/http://dx.doi.org/10.1016/j.apsusc.2005.02.067  
dc.relation.alternativeid
info:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/abs/pii/S0169433205003028