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dc.contributor.author
Riccardo, Jose Luis
dc.contributor.author
Romá, Federico José
dc.contributor.author
Ramirez Pastor, Antonio Jose
dc.date.available
2022-05-27T12:47:09Z
dc.date.issued
2005-12
dc.identifier.citation
Riccardo, Jose Luis; Romá, Federico José; Ramirez Pastor, Antonio Jose; Generalized statistical description of adsorption of polyatomics; Elsevier Science; Applied Surface Science; 252; 3; 12-2005; 505-511
dc.identifier.issn
0169-4332
dc.identifier.uri
http://hdl.handle.net/11336/158338
dc.description.abstract
Multisite-occupancy adsorption is described as a fractional statistic problem, based on Haldane’s statistics. Site exclusion is characterized by a statistical exclusion parameter, g, which relates to the molecular size and lattice geometry. A general adsorption isotherm is obtained and comparisons with experiments indicate that the spatial configuration of adsorbed molecules and lateral interactions may accurately be assessed from this theory. In addition, the theoretical framework developed in this paper allows to describe orientational transitions occurring in adlayers of polyatomics.
dc.format
application/pdf
dc.language.iso
eng
dc.publisher
Elsevier Science
dc.rights
info:eu-repo/semantics/openAccess
dc.rights.uri
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.subject
ADSORPTION ISOTHERMS
dc.subject
MULTISITE OCCUPANCY
dc.subject
QUANTUM FRACTIONAL STATISTICS
dc.subject
MONTE CARLO SIMULATIONS
dc.subject
EQUILIBRIUM THERMODYNAMICS AND STATISTICAL MECHANICS
dc.subject.classification
Física de los Materiales Condensados
dc.subject.classification
Ciencias Físicas
dc.subject.classification
CIENCIAS NATURALES Y EXACTAS
dc.title
Generalized statistical description of adsorption of polyatomics
dc.type
info:eu-repo/semantics/article
dc.type
info:ar-repo/semantics/artículo
dc.type
info:eu-repo/semantics/publishedVersion
dc.date.updated
2022-05-20T15:06:54Z
dc.journal.volume
252
dc.journal.number
3
dc.journal.pagination
505-511
dc.journal.pais
Países Bajos
dc.journal.ciudad
Amsterdam
dc.description.fil
Fil: Riccardo, Jose Luis. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - San Luis; Argentina. Universidad Nacional de San Luis. Facultad de Cs.fisico Matemáticas y Naturales. Laboratorio de Cs.de Superficies y Medios Porosos; Argentina
dc.description.fil
Fil: Romá, Federico José. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - San Luis; Argentina. Universidad Nacional de San Luis. Facultad de Cs.fisico Matemáticas y Naturales. Laboratorio de Cs.de Superficies y Medios Porosos; Argentina
dc.description.fil
Fil: Ramirez Pastor, Antonio Jose. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - San Luis; Argentina. Universidad Nacional de San Luis. Facultad de Cs.fisico Matemáticas y Naturales. Laboratorio de Cs.de Superficies y Medios Porosos; Argentina
dc.journal.title
Applied Surface Science
dc.relation.alternativeid
info:eu-repo/semantics/altIdentifier/doi/http://dx.doi.org/10.1016/j.apsusc.2005.02.067
dc.relation.alternativeid
info:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/abs/pii/S0169433205003028
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