Artículo
Bridging oxygens, the key to the electrical behaviour improvement of an ionic liquid - glass composite
Terny, Cintia Soledad
; Cardillo, Evangelina Cinthia
; Barolin, Sebastián Andrés
; Frechero, Marisa Alejandra
Fecha de publicación:
20/10/2021
Editorial:
Elsevier Science
Revista:
Colloids and Surfaces A: Physicochemical and Engineering Aspects
ISSN:
0927-7757
Idioma:
Inglés
Tipo de recurso:
Artículo publicado
Clasificación temática:
Resumen
The interactions between the [BMIM][PF6] -ionic liquid- and a phosphate glassy surface is studied through calorimetric, structural and impedance spectroscopy methods. A soft solid conductor material is obtained mixing the ionic glass powder with the ionic liquid in a low proportion (2 and 4%). At microscopic level, the interactions of this ionic liquid with the glassy particle surfaces reveal the formation of new bridging oxygens. Therefore, the material electrical conductivity increases in more than four orders of magnitude. This finding uncovers the essential elements to be considered before incorporating an additional salt to develop a solid electrolyte.
Palabras clave:
IL-GLASS INTERACCIONS
,
SOFT CONDUTOR
,
SOLID ELECTROLITE
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Identificadores
Colecciones
Articulos(INQUISUR)
Articulos de INST.DE QUIMICA DEL SUR
Articulos de INST.DE QUIMICA DEL SUR
Citación
Terny, Cintia Soledad; Cardillo, Evangelina Cinthia; Barolin, Sebastián Andrés; Frechero, Marisa Alejandra; Bridging oxygens, the key to the electrical behaviour improvement of an ionic liquid - glass composite; Elsevier Science; Colloids and Surfaces A: Physicochemical and Engineering Aspects; 627; 127208; 20-10-2021; 1-7
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