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dc.contributor.author
Ellena, J.  
dc.contributor.author
Kremer, E.  
dc.contributor.author
Facchin, G.  
dc.contributor.author
Baran, Enrique José  
dc.contributor.author
Nascimento, O. R.  
dc.contributor.author
Costa Filho, A. J.  
dc.contributor.author
Torre, M. H.  
dc.date.available
2022-04-20T20:43:51Z  
dc.date.issued
2007-08-06  
dc.identifier.citation
Ellena, J.; Kremer, E.; Facchin, G.; Baran, Enrique José; Nascimento, O. R.; et al.; X-ray structure and EPR behavior of a new dimeric copper(II) complex with 4-amino-N-(5-methoxy-2-pyrimidinyl)benzenesulfonamide; Elsevier; Polyhedron; 26; 13; 06-8-2007; 3277-3285  
dc.identifier.issn
0277-5387  
dc.identifier.uri
http://hdl.handle.net/11336/155474  
dc.description.abstract
A new complex, [Cu2(sulfameter)4]3 Æ 2.5H2O (sulfameter = 4-amino-N-(5-methoxy-2-pyrimidinyl)benzenesulfonamide), has been synthesized. Its structure has been determined by single-crystal X-ray diffraction and its spectroscopic properties (EPR, IR, Raman, UV–Vis) have been analyzed. The structure presented three different dimeric units in the unit cell and the EPR spectra, characteristic of antiferromagnetically coupled dimers, revealed two magnetically different dimeric environments.  
dc.format
application/pdf  
dc.language.iso
eng  
dc.publisher
Elsevier  
dc.rights
info:eu-repo/semantics/openAccess  
dc.rights.uri
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/  
dc.subject
Copper complexes  
dc.subject
Sulfameter  
dc.subject
Crystal structure  
dc.subject
EPR  
dc.subject.classification
Química Inorgánica y Nuclear  
dc.subject.classification
Ciencias Químicas  
dc.subject.classification
CIENCIAS NATURALES Y EXACTAS  
dc.title
X-ray structure and EPR behavior of a new dimeric copper(II) complex with 4-amino-N-(5-methoxy-2-pyrimidinyl)benzenesulfonamide  
dc.type
info:eu-repo/semantics/article  
dc.type
info:ar-repo/semantics/artículo  
dc.type
info:eu-repo/semantics/publishedVersion  
dc.date.updated
2021-12-03T19:59:28Z  
dc.journal.volume
26  
dc.journal.number
13  
dc.journal.pagination
3277-3285  
dc.journal.pais
Reino Unido  
dc.journal.ciudad
Amsterdam  
dc.description.fil
Fil: Ellena, J.. Universidade de Sao Paulo; Brasil  
dc.description.fil
Fil: Kremer, E.. Universidad de la República; Uruguay  
dc.description.fil
Fil: Facchin, G.. Universidad de la República; Uruguay  
dc.description.fil
Fil: Baran, Enrique José. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Química Inorgánica "Dr. Pedro J. Aymonino". Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Centro de Química Inorgánica "Dr. Pedro J. Aymonino"; Argentina  
dc.description.fil
Fil: Nascimento, O. R.. Universidade de Sao Paulo; Brasil  
dc.description.fil
Fil: Costa Filho, A. J.. Universidade de Sao Paulo; Brasil  
dc.description.fil
Fil: Torre, M. H.. Universidad de la República; Uruguay  
dc.journal.title
Polyhedron  
dc.relation.alternativeid
info:eu-repo/semantics/altIdentifier/doi/http://dx.doi.org/10.1016/j.poly.2007.03.005  
dc.relation.alternativeid
info:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/abs/pii/S027753870700143X?via%3Dihub