Artículo
Influence of Ti Incorporation to Bimetallic Mesoporous Carbon in the Production of 2,5-Dimethylfuran from Biomass Derivatives
Ledesma, Brenda Cecilia Soledad
; Juarez, Juliana
; Domine, Marcelo Eduardo; Beltramone, Andrea Raquel
Fecha de publicación:
24/07/2021
Editorial:
Springer
Revista:
Catalysis Letters
ISSN:
1011-372X
e-ISSN:
1572-879X
Idioma:
Inglés
Tipo de recurso:
Artículo publicado
Clasificación temática:
Resumen
Monometallic and bimetallic supported catalysts were developed to produce 2,5-dimethylfuran (DMF) trough hydrogenolysis of 5-(hydroxymethyl)furfural (HMF). Detailed physicochemical characterization was done to understand structure–activity correlation. Through a series of experiments and comparatives tests, the synergistic effect among Pt, Ir, and Ti incorporated in the support was investigated. Results revealed that using the titanium contained ordered mesoporous carbon, synthesized by a novel technique, high selectivity to DMF was achieved. In the case of the best catalyst PtIr-TiC, the good activity and excellent selectivity to the desired product DMF (98% yield) was related to the high hydrogenating capacity of the bimetallic sites, the acid support characteristics and the high metal nanoparticles dispersion achieved on the mesoporous titanium modified carbon support.
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Identificadores
Colecciones
Articulos(CCT - CORDOBA)
Articulos de CTRO.CIENTIFICO TECNOL.CONICET - CORDOBA
Articulos de CTRO.CIENTIFICO TECNOL.CONICET - CORDOBA
Citación
Ledesma, Brenda Cecilia Soledad; Juarez, Juliana; Domine, Marcelo Eduardo; Beltramone, Andrea Raquel; Influence of Ti Incorporation to Bimetallic Mesoporous Carbon in the Production of 2,5-Dimethylfuran from Biomass Derivatives; Springer; Catalysis Letters; 2021; 24-7-2021; 1-15
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