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dc.contributor.author
Kundu, Abhinanda
dc.contributor.author
Chandra, Shubhadeep
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Mandal, Debdeep
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Neuman, Nicolás Ignacio
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Mahata, Alok
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Anga, Srinivas
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Rawat, Hemant
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Pal, Sudip
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Schulzke, Carola
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Sarkar, Biprajit
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Chandrasekhar, Vadapalli
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Jana, Anukul
dc.date.available
2022-01-18T22:09:42Z
dc.date.issued
2021-09
dc.identifier.citation
Kundu, Abhinanda; Chandra, Shubhadeep; Mandal, Debdeep; Neuman, Nicolás Ignacio; Mahata, Alok; et al.; Twisted Push-Pull Alkenes Bearing Geminal Cyclicdiamino and Difluoroaryl Substituents; American Chemical Society; Journal of Organic Chemistry; 86; 18; 9-2021; 12683-12692
dc.identifier.issn
0022-3263
dc.identifier.uri
http://hdl.handle.net/11336/150279
dc.description.abstract
The systematic combination of N-heterocyclic olefins (NHOs) with fluoroarenes resulted in twisted push-pull alkenes. These alkenes carry electron-donating cyclicdiamino substituents and two electron-withdrawing fluoroaryl substituents in the geminal positions. The synthetic method can be extended to a variety of substituted push-pull alkenes by varying the NHO as well as the fluoroarenes. Solid-state molecular structures of these molecules reveal a notable elongation of the central C-C bond and a twisted geometry in the alkene motif. Absorption properties were investigated with UV-vis spectroscopy. The redox properties of the twisted push-pull alkenes were probed with electrochemistry as well as UV-vis/NIR and EPR spectroelectrochemistry, while the electronic structures were computationally evaluated and validated.
dc.format
application/pdf
dc.language.iso
eng
dc.publisher
American Chemical Society
dc.rights
info:eu-repo/semantics/openAccess
dc.rights.uri
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.subject
PUSH-PULL
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ALKENE
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FLUORINE
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Química Orgánica
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Ciencias Químicas
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CIENCIAS NATURALES Y EXACTAS
dc.title
Twisted Push-Pull Alkenes Bearing Geminal Cyclicdiamino and Difluoroaryl Substituents
dc.type
info:eu-repo/semantics/article
dc.type
info:ar-repo/semantics/artículo
dc.type
info:eu-repo/semantics/publishedVersion
dc.date.updated
2021-12-13T18:47:35Z
dc.journal.volume
86
dc.journal.number
18
dc.journal.pagination
12683-12692
dc.journal.pais
Estados Unidos
dc.journal.ciudad
Washington
dc.description.fil
Fil: Kundu, Abhinanda. International Centre Of Theoretical Science. Tata Institute Of Fundamental Research; España
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Fil: Chandra, Shubhadeep. Universitat Stuttgart; Alemania
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Fil: Mandal, Debdeep. International Centre Of Theoretical Science. Tata Institute Of Fundamental Research; España
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Fil: Neuman, Nicolás Ignacio. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Desarrollo Tecnológico para la Industria Química. Universidad Nacional del Litoral. Instituto de Desarrollo Tecnológico para la Industria Química; Argentina
dc.description.fil
Fil: Mahata, Alok. International Centre Of Theoretical Science. Tata Institute Of Fundamental Research; España
dc.description.fil
Fil: Anga, Srinivas. International Centre Of Theoretical Science. Tata Institute Of Fundamental Research; España
dc.description.fil
Fil: Rawat, Hemant. International Centre Of Theoretical Science. Tata Institute Of Fundamental Research; España
dc.description.fil
Fil: Pal, Sudip. International Centre Of Theoretical Science. Tata Institute Of Fundamental Research; España
dc.description.fil
Fil: Schulzke, Carola. ERNST MORITZ ARNDT UNIVERSITÄT GREIFSWALD (UG);
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Fil: Sarkar, Biprajit. Universität Stuttgart; Alemania
dc.description.fil
Fil: Chandrasekhar, Vadapalli. Indian Institute Of Technology Kanpur; India
dc.description.fil
Fil: Jana, Anukul. Tata Institute Of Fundamental Research, Hyderabad; India
dc.journal.title
Journal of Organic Chemistry
dc.relation.alternativeid
info:eu-repo/semantics/altIdentifier/doi/http://dx.doi.org/10.1021/acs.joc.1c01201
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