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dc.contributor.author
Caretti, Daniele
dc.contributor.author
Binda, Lorenzo
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Casis, Natalia
dc.contributor.author
Estenoz, Diana Alejandra
dc.date.available
2022-01-18T14:47:33Z
dc.date.issued
2021-09
dc.identifier.citation
Caretti, Daniele; Binda, Lorenzo; Casis, Natalia; Estenoz, Diana Alejandra; Novel monomers with N-methyl-D-glucamine segments and their application in structured porous materials for arsenic capture; John Wiley & Sons Inc; Journal of Applied Polymer Science; 139; 6; 9-2021; 1-10
dc.identifier.issn
0021-8995
dc.identifier.uri
http://hdl.handle.net/11336/150229
dc.description.abstract
The N-methyl-D-glucamine moieties exhibit high ability and selectivity toward arsenate ions in water by a complexation mechanism that involves their hydroxyl groups. In this work, the syntheses of two monomers containing N-methyl-D-glucamine, namely 4-vinylbenzyl-N-methyl-D-glucamine (VbNMDG), and N-methyl-D-glucamine methacrylamide (MNMDG) were studied. Different synthetic routes were considered in order to obtain liquid monomers able to polymerize and selectively capture arsenic. Furthermore, the incorporation of protective groups like trimethylsilyl moieties in the molecular structure was assessed to prevent transfer reactions during further polymerization. After polymerization, hydroxyl groups were deprotected using hydrofluoric acid. Following this methodology, structured microporous polymeric films based on colloidal crystal templates were prepared. NMR and FTIR techniques were used to follow the reactions and to determine the chemical structure of the obtained products. The morphology of materials was characterized by SEM. The performances of the developed polymeric films to selectively capture arsenic were determined. Films showed an improved and reproducible sensitivity to arsenic detection exhibiting high values of arsenic capturing capability (around 90%).
dc.format
application/pdf
dc.language.iso
eng
dc.publisher
John Wiley & Sons Inc
dc.rights
info:eu-repo/semantics/restrictedAccess
dc.rights.uri
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.subject
FUNCTIONALIZATION OF POLYMERS
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SENSORS AND ACTUATORS
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SYNTHESIS AND PROCESSING TECHNIQUES
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Ingeniería de Procesos Químicos
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Ingeniería Química
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INGENIERÍAS Y TECNOLOGÍAS
dc.title
Novel monomers with N-methyl-D-glucamine segments and their application in structured porous materials for arsenic capture
dc.type
info:eu-repo/semantics/article
dc.type
info:ar-repo/semantics/artículo
dc.type
info:eu-repo/semantics/publishedVersion
dc.date.updated
2021-12-13T18:50:32Z
dc.journal.volume
139
dc.journal.number
6
dc.journal.pagination
1-10
dc.journal.pais
Estados Unidos
dc.journal.ciudad
New York
dc.description.fil
Fil: Caretti, Daniele. Universidad de Bologna; Italia
dc.description.fil
Fil: Binda, Lorenzo. Universidad de Bologna; Italia
dc.description.fil
Fil: Casis, Natalia. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Desarrollo Tecnológico para la Industria Química. Universidad Nacional del Litoral. Instituto de Desarrollo Tecnológico para la Industria Química; Argentina
dc.description.fil
Fil: Estenoz, Diana Alejandra. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Desarrollo Tecnológico para la Industria Química. Universidad Nacional del Litoral. Instituto de Desarrollo Tecnológico para la Industria Química; Argentina
dc.journal.title
Journal of Applied Polymer Science
dc.relation.alternativeid
info:eu-repo/semantics/altIdentifier/doi/https://doi.org/10.1002/app.51610
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