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dc.contributor.author
Barata Vallejo, Sebastian
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dc.contributor.author
Yerien, Damián Emilio
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dc.contributor.author
Postigo, Jose Alberto
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dc.date.available
2021-12-06T17:22:33Z
dc.date.issued
2021-07
dc.identifier.citation
Barata Vallejo, Sebastian; Yerien, Damián Emilio; Postigo, Jose Alberto; Advances in Photocatalytic Organic Synthetic Transformations in Water and Aqueous Media; American Chemical Society; ACS Sustainable Chemistry and Engineering; 9; 30; 7-2021; 10016-10047
dc.identifier.issn
2168-0485
dc.identifier.uri
http://hdl.handle.net/11336/148309
dc.description.abstract
Advances in visible light-photocatalyzed preparative synthetic organic transformations in water or aqueous media are studied. Both the convenience of visible light photocatalytic strategies to achieve synthetic organic transformations and the employment of water or aqueous mixtures make this approach a very resourceful methodology. Mechanistic aspects for such photocatalyzed processes are discussed. The effects of water in the stereoselectivity of some reactions and considerations regarding the improved enantioselectivity in chiral catalytic photoredox reactions are manifested with the use of water. The use of water as a result of a protocol improvement or environmentally friendlier methodology as compared to the same reaction performed in organic solvents are also considered. All these combined effects of water as a reaction medium or its very presence in photocatalytic reactions have an ultimate goal which is to diminish the environmental impact of synthetic and photocatalytic processes. This perspective highlights the progress and state of the art organic transformations realized by photocatalytic techniques in water or aqueous systems as well as water as a reactant. In this regard, aromatic substitution reactions, radical additions to carbon-carbon double bonds, photooxidation reactions, decarboxylation processes, and miscellaneous reactions are presented.
dc.format
application/pdf
dc.language.iso
eng
dc.publisher
American Chemical Society
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dc.rights
info:eu-repo/semantics/openAccess
dc.rights.uri
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.subject
DECARBOXYLATIVE REACTIONS
dc.subject
DIASTEREOSELECTIVE PHOTOCATALYSIS
dc.subject
ENANTIOSELECTIVE PHOTOCATALYSIS
dc.subject
PHOTOCATALYSIS IN WATER
dc.subject
PHOTOCATALYZED ARYLATIONS
dc.subject
PHOTOCATALYZED ATRA
dc.subject
PHOTOCATALYZED CYCLIZATIONS
dc.subject
PHOTOCATALYZED DEOXYGENATIONS
dc.subject
PHOTOCATALYZED PHOTOOXIDATIONS
dc.subject.classification
Química Orgánica
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dc.subject.classification
Ciencias Químicas
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dc.subject.classification
CIENCIAS NATURALES Y EXACTAS
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dc.title
Advances in Photocatalytic Organic Synthetic Transformations in Water and Aqueous Media
dc.type
info:eu-repo/semantics/article
dc.type
info:ar-repo/semantics/artículo
dc.type
info:eu-repo/semantics/publishedVersion
dc.date.updated
2021-12-03T20:40:07Z
dc.journal.volume
9
dc.journal.number
30
dc.journal.pagination
10016-10047
dc.journal.pais
Estados Unidos
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dc.description.fil
Fil: Barata Vallejo, Sebastian. Universidad de Buenos Aires. Facultad de Farmacia y Bioquímica; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Houssay; Argentina
dc.description.fil
Fil: Yerien, Damián Emilio. Universidad de Buenos Aires. Facultad de Farmacia y Bioquímica; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Houssay; Argentina
dc.description.fil
Fil: Postigo, Jose Alberto. Universidad de Buenos Aires. Facultad de Farmacia y Bioquímica; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Houssay; Argentina
dc.journal.title
ACS Sustainable Chemistry and Engineering
dc.relation.alternativeid
info:eu-repo/semantics/altIdentifier/doi/http://dx.doi.org/10.1021/acssuschemeng.1c03384
dc.relation.alternativeid
info:eu-repo/semantics/altIdentifier/url/https://pubs.acs.org/doi/10.1021/acssuschemeng.1c03384
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