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dc.contributor.author
Bhattacharyya, Dhritiman  
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Videla, Pablo Ernesto  
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Cattaneo, Mauricio  
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Batista, Victor S.  
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Lian, Tianquan  
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Kubiak, Clifford P.  
dc.date.available
2021-11-25T13:32:21Z  
dc.date.issued
2021-07  
dc.identifier.citation
Bhattacharyya, Dhritiman; Videla, Pablo Ernesto; Cattaneo, Mauricio; Batista, Victor S.; Lian, Tianquan; et al.; Vibrational stark shift spectroscopy of catalysts under the influence of electric fields at electrode–solution interfaces; Royal Society of Chemistry; Chemical Science; 12; 30; 7-2021; 10131-10149  
dc.identifier.issn
2041-6520  
dc.identifier.uri
http://hdl.handle.net/11336/147393  
dc.description.abstract
External control of chemical processes is a subject of widespread interest in chemical research, including control of electrocatalytic processes with significant promise in energy research. The electrochemical double-layer is the nanoscale region next to the electrode/electrolyte interface where chemical reactions typically occur. Understanding the effects of electric fields within the electrochemical double layer requires a combination of synthesis, electrochemistry, spectroscopy, and theory. In particular, vibrational sum frequency generation (VSFG) spectroscopy is a powerful technique to probe the response of molecular catalysts at the electrode interface under bias. Fundamental understanding can be obtained via synthetic tuning of the adsorbed molecular catalysts on the electrode surface and by combining experimental VSFG data with theoretical modelling of the Stark shift response. The resulting insights at the molecular level are particularly valuable for the development of new methodologies to control and characterize catalysts confined to electrode surfaces. This Perspective article is focused on how systematic modifications of molecules anchored to surfaces report information concerning the geometric, energetic, and electronic parameters of catalysts under bias attached to electrode surfaces.  
dc.format
application/pdf  
dc.language.iso
eng  
dc.publisher
Royal Society of Chemistry  
dc.rights
info:eu-repo/semantics/openAccess  
dc.rights.uri
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/  
dc.subject
VIBRATIONAL STARK SHIFT SPECTROSCOPY  
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MOLECULAR CATALYSTS  
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INFLUENCE OF ELCTRIC FIELDS  
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ELECTRODE SURFACE  
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Físico-Química, Ciencia de los Polímeros, Electroquímica  
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Ciencias Químicas  
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CIENCIAS NATURALES Y EXACTAS  
dc.title
Vibrational stark shift spectroscopy of catalysts under the influence of electric fields at electrode–solution interfaces  
dc.type
info:eu-repo/semantics/article  
dc.type
info:ar-repo/semantics/artículo  
dc.type
info:eu-repo/semantics/publishedVersion  
dc.date.updated
2021-11-23T13:38:25Z  
dc.identifier.eissn
2041-6539  
dc.journal.volume
12  
dc.journal.number
30  
dc.journal.pagination
10131-10149  
dc.journal.pais
Reino Unido  
dc.journal.ciudad
Cambridge  
dc.description.fil
Fil: Bhattacharyya, Dhritiman. University of Emory; Estados Unidos  
dc.description.fil
Fil: Videla, Pablo Ernesto. University of Yale; Estados Unidos. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Instituto de Química, Física de los Materiales, Medioambiente y Energía. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Instituto de Química, Física de los Materiales, Medioambiente y Energía; Argentina  
dc.description.fil
Fil: Cattaneo, Mauricio. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Tucumán. Instituto de Química del Noroeste. Universidad Nacional de Tucumán. Facultad de Bioquímica, Química y Farmacia. Instituto de Química del Noroeste; Argentina  
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Fil: Batista, Victor S.. University of Yale; Estados Unidos  
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Fil: Lian, Tianquan. University of Emory; Estados Unidos  
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Fil: Kubiak, Clifford P.. University of California at San Diego; Estados Unidos  
dc.journal.title
Chemical Science  
dc.relation.alternativeid
info:eu-repo/semantics/altIdentifier/doi/http://dx.doi.org/10.1039/D1SC01876K  
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info:eu-repo/semantics/altIdentifier/url/https://pubs.rsc.org/en/content/articlelanding/2021/SC/D1SC01876K