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dc.contributor.author
Lanús Mendez Elizalde, Matías
dc.contributor.author
Acha, Carlos Enrique
dc.contributor.author
Molina, Fernando Víctor
dc.contributor.author
Antonel, Paula Soledad
dc.date.available
2021-11-05T10:46:44Z
dc.date.issued
2020-03
dc.identifier.citation
Lanús Mendez Elizalde, Matías; Acha, Carlos Enrique; Molina, Fernando Víctor; Antonel, Paula Soledad; Composites of Poly(3,4-ethylenedioxythiophene) and CoFe2O4 Nanoparticles: Composition Influence on Structural, Electrical, and Magnetic Properties; American Chemical Society; Journal of Physical Chemistry C; 124; 12; 3-2020; 6884-6895
dc.identifier.issn
1932-7447
dc.identifier.uri
http://hdl.handle.net/11336/146073
dc.description.abstract
Composites of magnetic CoFe2O4 nanoparticles (MNP) in a poly(3,4-ethylenedioxythiophene) matrix at different ratios have been synthesized. Composites were characterized by electron microscopy, X-ray diffraction, thermal analysis, electrical conductivity, magnetization, and magnetoresistance studies. In the composites the MNP appear clustered, with an interparticle distance essentially constant, but where two regimes are distinguished for cluster separation: for high MNP concentrations an intercluster separation similar to the interparticle distance is found, while for low MNP contents the distance between clusters is larger than the interparticle separation. The electrical conductivity increases with polymer content, but being always far lower than general effective medium theory expectations. This indicates that the effect of MNP effect on polymer conduction is probably related to the generation of mechanical stress both by introducing additional scattering centers and by producing different arrangement of the polymer chains, compared with the pure PEDOT. The magnetization studies reveal the existence of the RKKY interaction, which couples ferromagnetically the MNP located in a cluster, while the dipolar interaction dominates the interaction between clusters. Magnetoresistance was studied for these composites, with a maximum value close to 0.7% at 0.7 T for the lowest polymer content. The magnetoresistance correlates very well with the reversible part of the magnetization, indicating that its possible origin should be associated with polymer mechanical deformation due to the magnetic-field-induced rotation of the MNP.
dc.format
application/pdf
dc.language.iso
eng
dc.publisher
American Chemical Society
dc.rights
info:eu-repo/semantics/openAccess
dc.rights.uri
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.subject
PEDOT
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COMPOSITE
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MAGNETIC NANOPARTICLES
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ELECTRIC AND MAGNETIC PROPERTIES
dc.subject.classification
Físico-Química, Ciencia de los Polímeros, Electroquímica
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Ciencias Químicas
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CIENCIAS NATURALES Y EXACTAS
dc.title
Composites of Poly(3,4-ethylenedioxythiophene) and CoFe2O4 Nanoparticles: Composition Influence on Structural, Electrical, and Magnetic Properties
dc.type
info:eu-repo/semantics/article
dc.type
info:ar-repo/semantics/artículo
dc.type
info:eu-repo/semantics/publishedVersion
dc.date.updated
2021-09-07T18:44:50Z
dc.journal.volume
124
dc.journal.number
12
dc.journal.pagination
6884-6895
dc.journal.pais
Estados Unidos
dc.journal.ciudad
Washington
dc.description.fil
Fil: Lanús Mendez Elizalde, Matías. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Instituto de Química, Física de los Materiales, Medioambiente y Energía. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Instituto de Química, Física de los Materiales, Medioambiente y Energía; Argentina
dc.description.fil
Fil: Acha, Carlos Enrique. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Instituto de Física de Buenos Aires. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Instituto de Física de Buenos Aires; Argentina
dc.description.fil
Fil: Molina, Fernando Víctor. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Instituto de Química, Física de los Materiales, Medioambiente y Energía. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Instituto de Química, Física de los Materiales, Medioambiente y Energía; Argentina
dc.description.fil
Fil: Antonel, Paula Soledad. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Instituto de Química, Física de los Materiales, Medioambiente y Energía. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Instituto de Química, Física de los Materiales, Medioambiente y Energía; Argentina
dc.journal.title
Journal of Physical Chemistry C
dc.relation.alternativeid
info:eu-repo/semantics/altIdentifier/url/https://pubs.acs.org/doi/10.1021/acs.jpcc.9b11241
dc.relation.alternativeid
info:eu-repo/semantics/altIdentifier/doi/http://dx.doi.org/10.1021/acs.jpcc.9b11241
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