Artículo
Three novel Indium MOFs derived from diphenic acid: synthesis, crystal structures and supramolecular chemistry
Platero Prats, Ana E.; Bernini, Maria Celeste
; Medina, Manuela E.; López Torres, Elena; Gutierrez Puebla, Enrique; Monge, M. Angeles; Snejko, Natalia
![Icon](/themes/CONICETDigital/images/conicet.png)
Fecha de publicación:
04/2011
Editorial:
Royal Society Of Chemistry
Revista:
Crystengcomm
ISSN:
1466-8033
Idioma:
Inglés
Tipo de recurso:
Artículo publicado
Clasificación temática:
Resumen
Three In(III) MOFs based on diphenic acid and nitrogen-donor ancillary ligands were obtained as pure phases. Two of them have 1D chain structures, and the third forms 2D zig-zag layers. The different torsion angles adopted by the diphenic ligand along with the existence of several non-covalent interactions govern the crystal packing and determine the formation of a centrosymmetric one-dimensional compound (1) or a non-centrosymmetric helical chain-based compound (3). Reaction with 2,2′-bipyridyl under certain conditions leads also to the formation of two dimeric precursors (compounds 4 and 5). The topological study of all their nets is reported.
Palabras clave:
Mofs
,
Indio
,
Acido Difénico
,
Polímero de Coordinacion
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Identificadores
Colecciones
Articulos(INFAP)
Articulos de INST. DE FISICA APLICADA "DR. JORGE ANDRES ZGRABLICH"
Articulos de INST. DE FISICA APLICADA "DR. JORGE ANDRES ZGRABLICH"
Citación
Platero Prats, Ana E.; Bernini, Maria Celeste; Medina, Manuela E.; López Torres, Elena; Gutierrez Puebla, Enrique; et al.; Three novel Indium MOFs derived from diphenic acid: synthesis, crystal structures and supramolecular chemistry; Royal Society Of Chemistry; Crystengcomm; 13; 15; 4-2011; 4965-4972
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