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dc.contributor.author
Koopal, Luuk
dc.contributor.author
Tan, Wenfeng
dc.contributor.author
Avena, Marcelo Javier
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dc.date.available
2021-10-14T15:57:58Z
dc.date.issued
2020-06
dc.identifier.citation
Koopal, Luuk; Tan, Wenfeng; Avena, Marcelo Javier; Equilibrium mono- and multicomponent adsorption models: From homogeneous ideal to heterogeneous non-ideal binding; Elsevier Science; Advances In Colloid And Interface Science; 280; 6-2020; 1-48; 102138
dc.identifier.issn
0001-8686
dc.identifier.uri
http://hdl.handle.net/11336/143607
dc.description.abstract
Aqueous sorption processes play an important role in, for example, pollutant binding to natural nanoparticles, colloid stability, separation and enrichment of components and remediation processes. In this article, which is a tribute to Hans Lyklema, models of localized (ad)sorption of molecules and ions from aqueous solution on homogeneous and heterogeneous nanoparticles are presented. The discussed models range from ideal monocomponent sorption on homogeneous (Langmuir) and heterogeneous sites, to multicomponent ideal sorption on homogeneous and heterogeneous sites, multicomponent multisite ion complexation with charge distribution (CD-MUSIC) and non-ideal competitive adsorption on heterogeneous sites (NICA). Attention is also paid to lateral interaction, site-induced aggregation, binding stoichiometry and multilayer formation. Electrical double layer models are discussed in relation to ion binding on impermeable and permeable nanoparticles. Insight in models that can describe sorption of molecules and ions on nanoparticles leads to awareness of the limitations of using simple models for complex systems and is needed for the selection and application of an appropriate model for a given system. This is relevant for all practical sorption processes and for a better understanding of the role of natural nanoparticles in the binding of nutrients and pollutants.
dc.format
application/pdf
dc.language.iso
eng
dc.publisher
Elsevier Science
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dc.rights
info:eu-repo/semantics/restrictedAccess
dc.rights.uri
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.subject
MONOCOMPONENT ADSORPTION
dc.subject
MULTICOMPONENT ADSORPTION
dc.subject
HETEROGENEOUS BINDING SITES
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BINDING STOICHIOMETRY
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SITE-INDUCED AGGREGATION
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ION BINDING
dc.subject.classification
Físico-Química, Ciencia de los Polímeros, Electroquímica
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dc.subject.classification
Ciencias Químicas
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dc.subject.classification
CIENCIAS NATURALES Y EXACTAS
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dc.title
Equilibrium mono- and multicomponent adsorption models: From homogeneous ideal to heterogeneous non-ideal binding
dc.type
info:eu-repo/semantics/article
dc.type
info:ar-repo/semantics/artículo
dc.type
info:eu-repo/semantics/publishedVersion
dc.date.updated
2021-02-18T15:46:11Z
dc.journal.volume
280
dc.journal.pagination
1-48; 102138
dc.journal.pais
Países Bajos
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dc.journal.ciudad
Amsterdam
dc.description.fil
Fil: Koopal, Luuk. University and Research; Países Bajos
dc.description.fil
Fil: Tan, Wenfeng. Huazhong Agricultural University, Wuhan, China.; China
dc.description.fil
Fil: Avena, Marcelo Javier. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Instituto de Química del Sur. Universidad Nacional del Sur. Departamento de Química. Instituto de Química del Sur; Argentina
dc.journal.title
Advances In Colloid And Interface Science
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dc.relation.alternativeid
info:eu-repo/semantics/altIdentifier/url/https://linkinghub.elsevier.com/retrieve/pii/S0001868619303720
dc.relation.alternativeid
info:eu-repo/semantics/altIdentifier/doi/http://dx.doi.org/10.1016/j.cis.2020.102138
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