Artículo
Enhancing hydrogen evolution activity of Au(111) in alkaline media through molecular engineering of a 2D polymer
Alexa, Patrick; Lombardi, Juan Manuel
; Abufager, Paula Natalia
; Busnengo, Heriberto Fabio
; Grumelli, Doris Elda
; Vyas, Vijay S.; Haase, Frederik; Lotsch, Bettina V.; Gutzler, Rico; Kern, Klaus
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Fecha de publicación:
25/05/2020
Editorial:
John Wiley & Sons Inc
Revista:
Angewandte Chemie
ISSN:
1433-7851
Idioma:
Inglés
Tipo de recurso:
Artículo publicado
Clasificación temática:
Resumen
The electrochemical splitting of water holds promise for the storage of energy produced intermittently by renewable energy sources. The evolution of hydrogen currently relies on the use of platinum as a catalyst—which is scarce and expensive—and ongoing research is focused towards finding cheaper alternatives. In this context, 2D polymers grown as single layers on surfaces have emerged as porous materials with tunable chemical and electronic structures that can be used for improving the catalytic activity of metal surfaces. Here, we use designed organic molecules to fabricate covalent 2D architectures by an Ullmann-type coupling reaction on Au(111). The polymer-patterned gold electrode exhibits a hydrogen evolution reaction activity up to three times higher than that of bare gold. Through rational design of the polymer on the molecular level we engineered hydrogen evolution activity by an approach that can be easily extended to other electrocatalytic reactions.
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Articulos(INIFTA)
Articulos de INST.DE INV.FISICOQUIMICAS TEORICAS Y APLIC.
Articulos de INST.DE INV.FISICOQUIMICAS TEORICAS Y APLIC.
Citación
Alexa, Patrick; Lombardi, Juan Manuel; Abufager, Paula Natalia; Busnengo, Heriberto Fabio; Grumelli, Doris Elda; et al.; Enhancing hydrogen evolution activity of Au(111) in alkaline media through molecular engineering of a 2D polymer; John Wiley & Sons Inc; Angewandte Chemie; 59; 22; 25-5-2020; 8411-8415
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