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dc.contributor.author
Abdala, Paula Macarena  
dc.contributor.author
Fantini, Márcia C. A.  
dc.contributor.author
Craievich, Aldo Felix  
dc.contributor.author
Lamas, Diego Germán  
dc.date.available
2021-09-14T13:40:42Z  
dc.date.issued
2010-01-27  
dc.identifier.citation
Abdala, Paula Macarena; Fantini, Márcia C. A.; Craievich, Aldo Felix; Lamas, Diego Germán; Crystallite size-dependent phases in nanocrystalline ZrO2–Sc2O3; Royal Society of Chemistry; Physical Chemistry Chemical Physics; 12; 27-1-2010; 2822-2829  
dc.identifier.issn
1463-9076  
dc.identifier.uri
http://hdl.handle.net/11336/140308  
dc.description.abstract
ZrO2-10, 12 and 14 mol% Sc2O3 nanopowders were prepared by using a nitrate-lysine gel-combustion synthesis. These materials were studied by synchrotron X-ray powder diffraction (SXPD) and Raman spectroscopy after calcination at different temperatures from 650 to 1200 1C, which led to samples with different average crystallite sizes, up to about 100 nm. The results from SXPD and Raman analyses indicate that, depending on Sc2O3 content, the metastable t0 0-form of the tetragonal phase or the cubic phase are fully retained at room temperature in nanocrystalline powders, provided an average crystallite sizes lower than B30 nm. By contrast, powders with larger average crystallite sizes exhibit the stable rhombohedral, b and g, phases and do not retain or very partially retain the metastable t0 0 and cubic ones.  
dc.format
application/pdf  
dc.language.iso
eng  
dc.publisher
Royal Society of Chemistry  
dc.rights
info:eu-repo/semantics/openAccess  
dc.rights.uri
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/  
dc.subject
Nanoceramics  
dc.subject
ZrO2-Sc2O3  
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Metastable phases  
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Synchrotron X-ray powder diffraction  
dc.subject.classification
Nano-materiales  
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Nanotecnología  
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INGENIERÍAS Y TECNOLOGÍAS  
dc.title
Crystallite size-dependent phases in nanocrystalline ZrO2–Sc2O3  
dc.type
info:eu-repo/semantics/article  
dc.type
info:ar-repo/semantics/artículo  
dc.type
info:eu-repo/semantics/publishedVersion  
dc.date.updated
2021-01-27T19:17:38Z  
dc.identifier.eissn
1463-9084  
dc.journal.volume
12  
dc.journal.pagination
2822-2829  
dc.journal.pais
Reino Unido  
dc.journal.ciudad
Cambridge  
dc.description.fil
Fil: Abdala, Paula Macarena. Consejo Nacional de Investigaciones Científicas y Técnicas. Instituto de Investigaciones Científicas y Técnicas de las Fuerzas Armadas. Centro de Investigaciones en Sólidos; Argentina  
dc.description.fil
Fil: Fantini, Márcia C. A.. Universidade do Sao Paulo. Instituto de Fisica de Sao Carlos; Brasil  
dc.description.fil
Fil: Craievich, Aldo Felix. Universidade do Sao Paulo. Instituto de Fisica de Sao Carlos; Brasil  
dc.description.fil
Fil: Lamas, Diego Germán. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Patagonia Confluencia; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Instituto de Investigaciones Científicas y Técnicas de las Fuerzas Armadas. Centro de Investigaciones en Sólidos; Argentina  
dc.journal.title
Physical Chemistry Chemical Physics  
dc.relation.alternativeid
info:eu-repo/semantics/altIdentifier/url/https://pubs.rsc.org/en/content/articlelanding/2010/cp/b922541b  
dc.relation.alternativeid
info:eu-repo/semantics/altIdentifier/doi/http://dx.doi.org/10.1039/b922541b