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dc.contributor.author
Riccardo, Jose Luis
dc.contributor.author
Romá, Federico José
dc.contributor.author
Ramirez Pastor, Antonio Jose
dc.date.available
2021-07-30T12:02:05Z
dc.date.issued
2006-11
dc.identifier.citation
Riccardo, Jose Luis; Romá, Federico José; Ramirez Pastor, Antonio Jose; Adsorption of polyatomics: Theoretical approaches in model systems and applications; World Scientific; International Journal of Modern Physics B; 20; 28; 11-2006; 4709-4778
dc.identifier.issn
0217-9792
dc.identifier.uri
http://hdl.handle.net/11336/137429
dc.description.abstract
The adsorption of polyatomics on one- and two-dimensional lattices is studied by combining theoretical modeling, Monte-Carlo (MC), simulations and their correspondence with experimental results. In one dimension, the rigorous statistical thermodynamics of interacting chains has been presented. With respect to two-dimensional adsorption, six different models to study non-interacting adsorbates have been discussed: (i) an extension to two dimensions of the exact thermodynamic functions obtained in one dimension; (ii) the Flory-Huggins's approximation and its modification to address linear adsorbates; (iii) the well-known Guggenheim-DiMarzio approximation; (iv) the fourth one is a new description of adsorption phenomena, based on Haldane's fractional statistics; (v) the so-called Occupation Balance, based on the expansion of the reciprocal of the fugacity; and (vi) a simple semi-empirical model obtained by combining exact one-dimensional calculations and Guggenheim-DiMarzio approach. In addition, the statistical thermodynamics of interacting polyatomics has been developed on a generalization in the spirit of the Bragg-Williams and the quasi-chemical approximations. Comparison with MC simulations and experimental adsorption isotherms are used to test the accuracy and reliability of the proposed models. Finally, applications to heterogeneous systems and multilayer adsorption are discussed.
dc.format
application/pdf
dc.language.iso
eng
dc.publisher
World Scientific
dc.rights
info:eu-repo/semantics/openAccess
dc.rights.uri
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.subject
ADSORPTION
dc.subject
MULTISITE OCCUPANCY
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LATTICE-GAS MODELS
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CHAIN ADSORPTION
dc.subject.classification
Físico-Química, Ciencia de los Polímeros, Electroquímica
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Ciencias Químicas
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CIENCIAS NATURALES Y EXACTAS
dc.title
Adsorption of polyatomics: Theoretical approaches in model systems and applications
dc.type
info:eu-repo/semantics/article
dc.type
info:ar-repo/semantics/artículo
dc.type
info:eu-repo/semantics/publishedVersion
dc.date.updated
2021-07-29T13:55:15Z
dc.identifier.eissn
1793-6578
dc.journal.volume
20
dc.journal.number
28
dc.journal.pagination
4709-4778
dc.journal.pais
Singapur
dc.description.fil
Fil: Riccardo, Jose Luis. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - San Luis. Instituto de Física Aplicada "Dr. Jorge Andrés Zgrablich". Universidad Nacional de San Luis. Facultad de Ciencias Físico Matemáticas y Naturales. Instituto de Física Aplicada "Dr. Jorge Andrés Zgrablich"; Argentina
dc.description.fil
Fil: Romá, Federico José. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - San Luis. Instituto de Física Aplicada "Dr. Jorge Andrés Zgrablich". Universidad Nacional de San Luis. Facultad de Ciencias Físico Matemáticas y Naturales. Instituto de Física Aplicada "Dr. Jorge Andrés Zgrablich"; Argentina
dc.description.fil
Fil: Ramirez Pastor, Antonio Jose. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - San Luis. Instituto de Física Aplicada "Dr. Jorge Andrés Zgrablich". Universidad Nacional de San Luis. Facultad de Ciencias Físico Matemáticas y Naturales. Instituto de Física Aplicada "Dr. Jorge Andrés Zgrablich"; Argentina
dc.journal.title
International Journal of Modern Physics B
dc.relation.alternativeid
info:eu-repo/semantics/altIdentifier/url/https://www.worldscientific.com/doi/abs/10.1142/S0217979206035734
dc.relation.alternativeid
info:eu-repo/semantics/altIdentifier/doi/https://doi.org/10.1142/S0217979206035734
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