Artículo

Radical amination with trimethylstannylated benzophenone imine

Lamas, Marie-Céline; Vaillard, Santiago EduardoIcon ; Wibbeling, Birgit; Studer, Armido
Fecha de publicación: 04/2010
Editorial: American Chemical Society
Revista: Organic Letters
ISSN: 1523-7060
Idioma: Inglés
Tipo de recurso: Artículo publicado
Clasificación temática:

Resumen

Intermolecular radical amination reactions of various primary, secondary, and tertiary alkyl radicals by using trimethylstannylated benzophenone imine A as a novel radical acceptor to provide imines of type B are described. These imines are readily reduced with NaBH4 to the corresponding secondary amines C. The novel radical amination can be combined with typical radical cyclization reactions.
Palabras clave: Homolytic Substitution , Amination , Imines , Radicals
 
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info:eu-repo/semantics/openAccess Excepto donde se diga explícitamente, este item se publica bajo la siguiente descripción: Creative Commons Attribution-NonCommercial-ShareAlike 2.5 Unported (CC BY-NC-SA 2.5)
Identificadores
URI: http://hdl.handle.net/11336/13703
DOI: http://dx.doi.org/10.1021/ol1005455
URL: http://pubs.acs.org/doi/abs/10.1021/ol1005455
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Articulos de INST.DE DES.TECNOL.PARA LA IND.QUIMICA (I)
Citación
Lamas, Marie-Céline; Vaillard, Santiago Eduardo; Wibbeling, Birgit; Studer, Armido; Radical amination with trimethylstannylated benzophenone imine; American Chemical Society; Organic Letters; 12; 9; 4-2010; 2072-2075
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