Artículo
Limit of Applicability of the Monomer-Enhanced Mechanism for Radical Generation in Persulfate Initiated Polymerization of Acrylamide
Fecha de publicación:
10/2010
Editorial:
Planta Piloto de Ingeniería Química
Revista:
Latin American Applied Research
ISSN:
0327-0793
e-ISSN:
1851-8796
Idioma:
Inglés
Tipo de recurso:
Artículo publicado
Clasificación temática:
Resumen
The limit of applicability of the monomer-enhanced mechanism as dominant mechanism ruling the initiation process of the polymerization of acrylamide (AM) initiated with potassium persulfate (K2S2O8) has been determined. The kinetics and mechanisms for radical generation were studied in solution at very low monomer and initiator concentrations. The transition of the initiation mechanism from dominant monomer-enhanced dissociation to dominant thermal decomposition of persulfate was observed. Both mechanisms contribute equally to radical generation at [AM] / [K2S2O8] = 4.5. Thermal decomposition dominates at lower [AM] or higher [K2S2O8] and opposite variations promote the monomer-enhanced dissociation. This work also includes quantification of the rate coefficients, efficiencies and activation energies of the mentioned mechanisms, and the kinetics of AM polymerization when photochemically initiated with phenylbis(2,4,6-trimethylbenzoyl)-phosphine oxide.
Palabras clave:
Kinetics
,
Mechanism
,
Initiation
,
Acrylamide
,
Persulfate
Archivos asociados
Licencia
Identificadores
Colecciones
Articulos(INTEC)
Articulos de INST.DE DES.TECNOL.PARA LA IND.QUIMICA (I)
Articulos de INST.DE DES.TECNOL.PARA LA IND.QUIMICA (I)
Citación
Rintoul, Ignacio; Wandrey, Christine; Limit of Applicability of the Monomer-Enhanced Mechanism for Radical Generation in Persulfate Initiated Polymerization of Acrylamide; Planta Piloto de Ingeniería Química; Latin American Applied Research; 40; 4; 10-2010; 365-372
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