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dc.contributor.author
Cordero Sánchez, Salomon
dc.contributor.author
Rojas González, Fernando
dc.contributor.author
Kornhauser, Isaac
dc.contributor.author
Domínguez, Armando
dc.contributor.author
Vidales, Ana Maria
dc.contributor.author
López, Raúl Horacio
dc.contributor.author
Zgrablich, Giorgio
dc.contributor.author
Riccardo, Jose Luis
dc.date.available
2021-07-19T21:59:49Z
dc.date.issued
2002-08-15
dc.identifier.citation
Cordero Sánchez, Salomon; Rojas González, Fernando; Kornhauser, Isaac; Domínguez, Armando; Vidales, Ana Maria; et al.; Pore-blocking and pore-assisting factors during capillary condensation and evaporation; Elsevier Science; Applied Surface Science; 196; 1-4; 15-8-2002; 224-238
dc.identifier.issn
0169-4332
dc.identifier.uri
http://hdl.handle.net/11336/136447
dc.description.abstract
Thirty-four years ago Everett [The Solid-Gas Interface, Vol. 2, Marcel Dekker, New York, 1967, p. 1055] proposed a pore-blocking factor when establishing the foundations of a non-independent domain theory (IDT) of sorption hysteresis. Such pore-blocking factor was defined as the ratio between two desorbed volumes within the same pressure range. The first volume arose from a non-independent pore structure. The second quantity was a virtual one since it represented the volume desorbed if the pores of the substrate had acted as independent domains. In fact, Everett calculated the ratio between pore-blocking factors, while not their absolute values, from experimental data proceeding from sorption results on porous glasses. The astonishing conclusion of all this preliminary work, was that blocking factors depended upon the total amount of condensate at a certain stage of a desorption process rather than on the distribution of it within the porous network. In this way, a unique pore-blocking factor curve ensued from different sorption processes such as boundary and scanning curves. Now, through the aid of simulated heterogeneous 3-D porous networks and the sorption curves thereon developed, an assessment of the above mentioned important assertion has been undertaken. Besides, a pore-assisting factor that may arise during an ascending sorption process has been treated under a similar context.
dc.format
application/pdf
dc.language.iso
eng
dc.publisher
Elsevier Science
dc.rights
info:eu-repo/semantics/openAccess
dc.rights.uri
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.subject
ASSISTED CAPILLARY CONDENSATION
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DELAYED ADSORPTION
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HETEROGENEOUS POROUS NETWORKS
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PORE BLOCKING
dc.subject.classification
Físico-Química, Ciencia de los Polímeros, Electroquímica
dc.subject.classification
Ciencias Químicas
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CIENCIAS NATURALES Y EXACTAS
dc.title
Pore-blocking and pore-assisting factors during capillary condensation and evaporation
dc.type
info:eu-repo/semantics/article
dc.type
info:ar-repo/semantics/artículo
dc.type
info:eu-repo/semantics/publishedVersion
dc.date.updated
2021-03-15T14:40:36Z
dc.journal.volume
196
dc.journal.number
1-4
dc.journal.pagination
224-238
dc.journal.pais
Países Bajos
dc.journal.ciudad
Amsterdam
dc.description.fil
Fil: Cordero Sánchez, Salomon. Universidad Autónoma Metropolitana; México
dc.description.fil
Fil: Rojas González, Fernando. Universidad Autónoma Metropolitana; México
dc.description.fil
Fil: Kornhauser, Isaac. Universidad Autónoma Metropolitana; México
dc.description.fil
Fil: Domínguez, Armando. Universidad Autónoma Metropolitana; México
dc.description.fil
Fil: Vidales, Ana Maria. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - San Luis. Instituto de Física Aplicada "Dr. Jorge Andrés Zgrablich". Universidad Nacional de San Luis. Facultad de Ciencias Físico Matemáticas y Naturales. Instituto de Física Aplicada "Dr. Jorge Andrés Zgrablich"; Argentina
dc.description.fil
Fil: López, Raúl Horacio. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - San Luis. Instituto de Física Aplicada "Dr. Jorge Andrés Zgrablich". Universidad Nacional de San Luis. Facultad de Ciencias Físico Matemáticas y Naturales. Instituto de Física Aplicada "Dr. Jorge Andrés Zgrablich"; Argentina
dc.description.fil
Fil: Zgrablich, Giorgio. Universidad Nacional de San Luis. Facultad de Ciencias Físico Matemáticas y Naturales. Departamento de Física; Argentina
dc.description.fil
Fil: Riccardo, Jose Luis. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - San Luis. Instituto de Física Aplicada "Dr. Jorge Andrés Zgrablich". Universidad Nacional de San Luis. Facultad de Ciencias Físico Matemáticas y Naturales. Instituto de Física Aplicada "Dr. Jorge Andrés Zgrablich"; Argentina
dc.journal.title
Applied Surface Science
dc.relation.alternativeid
info:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/abs/pii/S0169433202000612
dc.relation.alternativeid
info:eu-repo/semantics/altIdentifier/doi/https://doi.org/10.1016/S0169-4332(02)00061-2
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