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dc.contributor.author
Postigo, Jose Alberto
dc.date.available
2017-02-20T19:33:59Z
dc.date.issued
2011-07
dc.identifier.citation
Postigo, Jose Alberto; Synthetically useful carbon-carbon and carbon-sulphur bond constructions mediated by carbon- and sulphur-centred radicals in water and aqueous media; Royal Society of Chemistry; RSC Advances; 1; 1; 7-2011; 14-32
dc.identifier.issn
2046-2069
dc.identifier.uri
http://hdl.handle.net/11336/13183
dc.description.abstract
This account is focused on carbon-carbon, and carbon-sulphur bond-forming reactions through the use of carbon- and sulphur-centred radicals in water, respectively. It intends to show the scope and applications on these types of radicals with a synthetic goal, thus helping the Radical Synthetic Chemist to grab the fundamental aspects devoted to the synthesis of a wide array of organic compounds through radical methods in environmentally friendly media. This account excludes the syntheses of organic substrates through the aid of organometallic / metal-centred radicals such as other Group IV-radicals and transition-metal radicals, and the important class of radical reductions currently accomplished in water through different metallic reducing species. The array of substrates synthesized through the present method encompasses intermolecular and intramolecular radical carbon-carbon bond formation reactions in water, and radical carbon-sulphur bond formation reactions. Among the radical carbon-carbon bond formation reactions, special attention is devoted to atom-transfer radical reactions, radical addition reactions to olefins, radical addition to carbon-nitrogen double bonds, and carboaminohydroxylation of alkenes, and the analogues of Knovonoegel reactions, synthesis of functionalized enol ethers, carboazidation and azidation, and ynol formation, and radical cyclization reactions in water.
dc.format
application/pdf
dc.language.iso
eng
dc.publisher
Royal Society of Chemistry
dc.rights
info:eu-repo/semantics/openAccess
dc.rights.uri
https://creativecommons.org/licenses/by-nc/2.5/ar/
dc.subject
Carbon-Centred Radicals
dc.subject
Sulphur Centred Radicals
dc.subject
Radical Reactions in Water
dc.subject.classification
Química Orgánica
dc.subject.classification
Ciencias Químicas
dc.subject.classification
CIENCIAS NATURALES Y EXACTAS
dc.title
Synthetically useful carbon-carbon and carbon-sulphur bond constructions mediated by carbon- and sulphur-centred radicals in water and aqueous media
dc.type
info:eu-repo/semantics/article
dc.type
info:ar-repo/semantics/artículo
dc.type
info:eu-repo/semantics/publishedVersion
dc.date.updated
2017-02-15T14:08:30Z
dc.journal.volume
1
dc.journal.number
1
dc.journal.pagination
14-32
dc.journal.pais
Reino Unido
dc.journal.ciudad
Chichester
dc.description.fil
Fil: Postigo, Jose Alberto. Universidad de Buenos Aires. Facultad de Farmacia y Bioquímica; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Houssay; Argentina
dc.journal.title
RSC Advances
dc.relation.alternativeid
info:eu-repo/semantics/altIdentifier/url/http://pubs.rsc.org/en/Content/ArticleLanding/2011/RA/C1RA00372K#!divAbstract
dc.relation.alternativeid
info:eu-repo/semantics/altIdentifier/url/http://dx.doi.org/10.1039/C1RA00372K
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