Artículo
Exchange Interactions Through π π Stacking in the Lamellar Compound [{Cu(bipy)(en)}{Cu(bipy)(H2O)}{VO3}4]n
Venegas Yazighi, Diego; Brown, Kareen; Vega, Andrés; Calvo, Rafael
; Aliaga, Carolina; Santana, Ricardo; Cardoso Gil, Raul; Kniep, Rüdiger ; Schnelle, Walter; Spodine, Evgenia
Fecha de publicación:
12/2011
Editorial:
American Chemical Society
Revista:
Inorganic Chemistry
ISSN:
0020-1669
Idioma:
Inglés
Tipo de recurso:
Artículo publicado
Clasificación temática:
Resumen
Structural, magnetic, and powder and single crystal electronic paramagnetic resonance (EPR) studies are reported for [{Cu(bipy)(en)}{Cu(bipy)(H2O)}{VO3}4]n, a new copper-vanadium hybrid organic-inorganic compound containing CuII and VV centers. This first single crystal EPR study of an oxovanadium based organo-inorganic hybrid material functionalized with CuII complexes allows evaluating extremely weak exchange couplings and observing a dimensional quantum phase transition.
Palabras clave:
Material Hibrido
,
Cobre-Vanadio
,
Apilamiento
,
Magnetismo
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Identificadores
Colecciones
Articulos(INTEC)
Articulos de INST.DE DES.TECNOL.PARA LA IND.QUIMICA (I)
Articulos de INST.DE DES.TECNOL.PARA LA IND.QUIMICA (I)
Citación
Venegas Yazighi, Diego; Brown, Kareen; Vega, Andrés; Calvo, Rafael; Aliaga, Carolina; et al.; Exchange Interactions Through π π Stacking in the Lamellar Compound [{Cu(bipy)(en)}{Cu(bipy)(H2O)}{VO3}4]n; American Chemical Society; Inorganic Chemistry; 50; 22; 12-2011; 11461-11471
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