Artículo

Radical fluoroalkylation reactions of (hetero)arenes and sulfides under red light photocatalysis

Yerien, Damián EmilioIcon ; Cooke, María VictoriaIcon ; Garcia Vior, María CeciliaIcon ; Barata Vallejo, SebastianIcon ; Postigo, Jose AlbertoIcon
Fecha de publicación: 03/2019
Editorial: Royal Society of Chemistry
Revista: Organic & Biomolecular Chemistry
ISSN: 1477-0520
Idioma: Inglés
Tipo de recurso: Artículo publicado
Clasificación temática:

Resumen

Fluoroalkylation reactions of (hetero)aromatics have been accomplished through the low-power illumination from red LEDs (λ max = 635 nm) of commercially available perfluoroalkyl iodides R F -I and phthalocyanine zinc salt as photocatalyst in MeCN : DMF solvent mixture. This methodology has been extended to the perfluorobutylation of sulfides. As far as we are concerned, this is the first report on a perfluoroalkylation reaction of (hetero)aromatics and sulfides under red-light photocatalysis.
Palabras clave: Radical perfluoroalkylation
 
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info:eu-repo/semantics/openAccess Excepto donde se diga explícitamente, este item se publica bajo la siguiente descripción: Creative Commons Attribution-NonCommercial-ShareAlike 2.5 Unported (CC BY-NC-SA 2.5)
Identificadores
URI: http://hdl.handle.net/11336/129274
URL: http://pubs.rsc.org/en/Content/ArticleLanding/2019/OB/C9OB00486F
DOI: http://dx.doi.org/ 10.1039/c9ob00486f
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Citación
Yerien, Damián Emilio; Cooke, María Victoria; Garcia Vior, María Cecilia; Barata Vallejo, Sebastian; Postigo, Jose Alberto; Radical fluoroalkylation reactions of (hetero)arenes and sulfides under red light photocatalysis; Royal Society of Chemistry; Organic & Biomolecular Chemistry; 17; 15; 3-2019; 3741-3746
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